2-[(N,N-dimethylaminomethyl)phenyl]di-tert-butylstannylfluoride | 712351-40-1

• 英文名称: 2-[(N,N-dimethylaminomethyl)phenyl]di-tert-butylstannylfluoride
• CAS: 712351-40-1
• 化学式: C₁₇H₃₀FNSn
• 分子量: 386.14
• InChiKey: ZOTIPUWTTUULKX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium fluoride 、 [2-(N,N-dimethylaminomethyl)phenyl]di-t-butyltin(IV) chloride 以 乙醚 、 水 为溶剂， 以69%的产率得到2-[(N,N-dimethylaminomethyl)phenyl]di-tert-butylstannylfluoride
  参考文献：
  名称：

  Monomeric Triorganotin(IV) Fluorides Containing a C,N-Chelating Ligand

  摘要：

  The set of four triorganotin(IV) fluorides of general formula {2-[(CH3)(2)NCH2]C6H4}R2SnF, where R is Me (5), n-Bu (6), t-Bu (7), and Ph (8), respectively, has been prepared and characterized using NMR and ESI-MS techniques. The structures of crystalline compounds 5 and 8 were determined using X-ray methods. All compounds are monomeric both in solution using different solvents and in the solid state. The tin central atom is five-coordinated with all carbon atoms in equatorial positions and fluorine and nitrogen, from the intramolecularly coordinated dimethylamino group, in the axial positions of the distorted trigonal bipyramid. The ability of compounds 6 and 8 to perform fluorination of organometallic chlorides was tested on titanocene dichloride. A quantitative yield Of CP2TiF2 was obtained.

  DOI：

  10.1021/om049912q