μ₂, μ₂-oxobis[(propiolato)triphenylantimony] | 1584694-41-6

• 英文名称: μ₂, μ₂-oxobis[(propiolato)triphenylantimony]
• 英文别名: [Ph₃SbOC(O)CCH]₂O
• CAS: 1584694-41-6
• 化学式: C₄₂H₃₂O₅Sb₂
• 分子量: 860.213
• InChiKey: SCZUSTOUGQVYFR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三苯基锑 、 丙炔酸 在 双氧水 作用下， 以 乙醚 、 水 为溶剂， 反应 24.0h， 以80%的产率得到μ₂, μ₂-oxobis[(propiolato)triphenylantimony]
  参考文献：
  名称：

  Tri- and tetraphenylantimony propiolates: Syntheses and structures

  摘要：

  The reaction of triphenylantimony with propiolic acid in the presence of hydrogen peroxide (molar ratios 1 : 2 : 1 and 1 : 1 : 1) in diethyl ether affords triphenylantimony dipropiolate Ph3Sb[OC(O)Ca parts per thousand CH](2) (I) and mu(2)-oxobis[(propiolato)triphenylantimony] [Ph3SbOC(O)Ca parts per thousand CH](2)O (II). Tetraphenylantimony propiolate Ph4SbOC(O)Ca parts per thousand CH (III) is synthesized from pentaphenylantimony and propiolic or acetylenedicarboxylic acid in toluene. According to the X-ray diffraction data, the crystals of compounds I and III include two types of crystallographically independent molecules (a and b). The antimony atoms in molecules Ia, Ib, II, IIIa, and IIIb have the trigonal-bipyramidal coordination mode with different degrees of distortion. The OSbO and OSbC axial angles are 176.8(2)A degrees (Ia, Ib), 170.17(15)A degrees, 178.78(14)A degrees (II), and 173.2(5)A degrees, 174.4(5)A degrees (IIIa, IIIb). The CSbC equatorial angles lie in the ranges 108.2(3)A degrees aEuro"143.1(3)A degrees (I), 109.0(2)A degrees aEuro"131.0(2)A degrees (II), and 113.1(4)A degrees aEuro"125.4(4)A degrees (III). The SbOSb angle in II is 141.55(19)A degrees. The Sb-C bond lengths are 2.103(8)-2.141(5) (I), 2.105(5)-2.119(5) (II), and 2.076(12)-2.166(13) (III). The Sb-O distances increase in a series of I, II, and III: 2.139(6)-2.156(7) (Ia, Ib); 2.206(4), 2.218(3) (II); and 2.338(10), 2.340(10) (III).

  DOI：

  10.1134/s1070328414020109