[RuCl₂(κ-P(t-Bu)MeCH₂CH₂-η⁶-C₆H₅)] | 1021183-45-8

• 英文名称: [RuCl₂(κ-P(t-Bu)MeCH₂CH₂-η⁶-C₆H₅)]
• 英文别名: dichloro(κP-η6-(R)-tert-butyl(2-phenylethyl)methylphosphine)ruthenium(II)
• CAS: 1021183-45-8
• 化学式: C₁₃H₂₁Cl₂PRu
• 分子量: 380.26
• InChiKey: BXNRICHSGBAUSH-ZSOSHZMMSA-L

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 [RuCl₂(κ-P(t-Bu)MeCH₂CH₂-η⁶-C₆H₅)] 、 三苯基膦 以 二氯甲烷 为溶剂， 生成 [RuCl(PPh3)((R)-tert-butyl(2-phenylethyl)methylphosphine)]PF6
  参考文献：
  名称：

  Synthesis and Reactivity of P-Chiral Tethered (η¹:η⁶-phosphinoarene)ruthenium Complexes

  摘要：

  A new group of tethered phosphinoarene ruthenium complexes containing a stereogenic center at the phosphine atom is presented. The introduction of other elements of chirality, either as a plane or at the ruthenium center, is explored.

  DOI：

  10.1021/om800076x
• 作为产物：
  描述：

  dichloro(η6-p-cymene)((R)-tert-butyl(2-phenylethyl)methylphosphine)ruthenium(II) 以 氯苯 为溶剂， 以66%的产率得到[RuCl₂(κ-P(t-Bu)MeCH₂CH₂-η⁶-C₆H₅)]
  参考文献：
  名称：

  Synthesis and Reactivity of P-Chiral Tethered (η¹:η⁶-phosphinoarene)ruthenium Complexes

  摘要：

  A new group of tethered phosphinoarene ruthenium complexes containing a stereogenic center at the phosphine atom is presented. The introduction of other elements of chirality, either as a plane or at the ruthenium center, is explored.

  DOI：

  10.1021/om800076x