copper(3-cyano-1,5-bis(2-methoxyphenyl)formazanato)chloride | 1010400-61-9

• 英文名称: copper(3-cyano-1,5-bis(2-methoxyphenyl)formazanato)chloride
• CAS: 1010400-61-9
• 化学式: C₁₆H₁₄ClCuN₅O₂
• 分子量: 407.318
• InChiKey: XPMMXZNEOZRLRL-QNKGGAOWSA-M

反应信息

• 作为产物：
  描述：

  1,5-bis(o-methoxyphenyl)-3-cyanoformazan 、 copper dichloride 在 NaH 作用下， 以 四氢呋喃 为溶剂， 以75.9%的产率得到copper(3-cyano-1,5-bis(2-methoxyphenyl)formazanato)chloride
  参考文献：
  名称：

  Transition Metal Complexes of 3-Cyano- and 3-Nitroformazans

  摘要：

  The synthesis and characterization of six transition metal complexes of 3-cyano- and 3-nitroformazans are described. Three different formazans were reacted with nickel(II) to produce complexes with bidentate formazan ligands. Mononuclear NiL2 (L = deprotonated formazan) or binuclear hydroxo-bridged (LNi)(2)(mu-OH)(2) species were produced depending on the steric bulk on the formazan N-aromatic substituents. 1,5-Bis(2-methoxyphenyl)-3-cyanoformazan acts as a tetradentate monoanionic ligand in a copper(II) complex, whereas the analogous 1,5-bis(2-hydroxyphenyl)-3-cyanoformazan binds as a trianion in a tetradentate manner to Fe(III) and Co(III). Crystal structures-the first examples of metal complexes of cyano- or nitroformazans-as well as the electronic spectra of the complexes are discussed in relation to each other as well as that of the uncoordinated formazans.

  DOI：

  10.1021/ic7019846