Re2(μ-H)[μ-(t-Bu)PC6H4PH(t-Bu)](CO)7 | 210529-08-1

• 英文名称: Re2(μ-H)[μ-(t-Bu)PC6H4PH(t-Bu)](CO)7
• CAS: 210529-08-1
• 化学式: C₂₁H₂₄O₇P₂Re₂
• 分子量: 822.779
• InChiKey: ZNKXCNKSBUFNGZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  十羰基二铼 、 1,2-bis(tert-butylphosphino)benzene 以 xylene 为溶剂， 以61.3%的产率得到Re2(μ-H)[μ-(t-Bu)PC6H4PH(t-Bu)](CO)7
  参考文献：
  名称：

  Synthesis of a dinuclear, phosphido-bridged complex of rhenium, X-ray crystal structure of Re2 (μ-H) [μ-(t-Bu)PC6H4P(H)t-Bu](CO)7

  摘要：

  The thermal reaction of Re-2(CO)(10) and 1,2-[t-BuPH](2)C6H4 in xylene gives Re-2(mu-H)[mu-(t-BuP)C6H4(t-BuPH)] (CO)(7) (1) in 70% yield. The crystal structure of 1 has been determined. Compound 1 crystallized in the monoclinic space group P2(1)/n with Z = 4; a = 10.953(3), b = 13.271(4), c = 17.969(7) Angstrom; beta = 104.48(2)degrees. The final R and R-w were 0.037 and 0.036, respectively. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(97)06158-6