[Tl2(μ-4,4'-thiodiphenol-H)2(H2O)]n | 956226-13-4

• 英文名称: [Tl2(μ-4,4'-thiodiphenol-H)2(H2O)]n
• 英文别名: [Tl2(μ-Htdp)2(H2O)]n
• CAS: 956226-13-4
• 化学式: C₂₄H₂₀O₅S₂Tl₂
• 分子量: 861.318
• InChiKey: HCYLXKQAFGTGFY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  thallium(I) nitrate 、 4,4'-二羟基二苯硫醚 、 水 在 KOH 作用下， 以 水 、 乙腈 为溶剂， 以40%的产率得到[Tl2(μ-4,4'-thiodiphenol-H)2(H2O)]n
  参考文献：
  名称：

  [Tl2(μ-Htdp)2(μ-H2O)]n (H2tdp=4,4′-thiodiphenol) – A one-dimensional thallium(I) coordination polymer with a large tetranuclear metallacycle: Thermal, emission and structural studies

  摘要：

  [Tl-2(mu-Htdp)(2)(mu-H2O)](n) (H(2)tdp = 4,4'-thiodiphenol) (1), a new rarely reported Tl-I one-dimensional coordination polymer with a large tetranuclear metallacycle, has been synthesized, characterized by elemental analysis and IR spectroscopy and its structure determined by single-crystal X-ray diffraction. The thermal stability of compound 1 was studied by thermal gravimetric (TG) and differential thermal analyses (DTA). The single crystal X-ray analysis of compound 1 shows that the complex consists of horseshoe-shaped (mu-Htdp)Tl(mu-H2O)Tl(mu-Htdp) subunits. Solid-state luminescent spectra of the ligand H(2)tdp and compound 1 indicate emission band with the maximum intensity at 475 and 465 nm upon excitation at 300 nm, respectively. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2006.10.014