benzoylbis(triisopropyl-l5-phosphaneyl)rhodium(V) chloride hydride | 171735-79-8

• 英文名称: benzoylbis(triisopropyl-l5-phosphaneyl)rhodium(V) chloride hydride
• CAS: 171735-79-8
• 化学式: C₂₅H₄₈ClOP₂Rh
• 分子量: 564.962
• InChiKey: GFDJFRNRBXOSSW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(triisopropylphosphine)rhodium chloride dimer 、 苯甲醛 在 PiPr₃ 作用下， 以 甲苯 为溶剂， 生成 benzoylbis(triisopropyl-l5-phosphaneyl)rhodium(V) chloride hydride
  参考文献：
  名称：

  将醛和酰氯加到[Rh（PiPr3）2Cl] 2中。Rh（PiPr3）2ClX [C（O）Ph]（X = H，Cl）的热力学以及分子和晶体结构

  摘要：

  Addition of aldehyde (RCHO; R = n-octyl, Ph, p-Tol, p-MeOC(6)H(4), p-CF3C6H4) to [Rh((PPr3)-Pr-i)(2)Cl](2) (1) results in rapid addition of the aldehyde C-H bond to yield Rh((PPr3)-Pr-i)(2)-ClH[C(O)R] (2-R). 2-Ph was isolated, and a single-crystal X-ray diffraction study reveals a trigonal-bipyramidal structure with a small H-Rh-C(acyl) angle of 85(4)degrees. Enthalpies of addition to 1 were measured by solution calorimetry (R, Delta H/(kcal/mol)): octyl, -15.2 +/- 0.3; Ph, -10.8 +/- 0.4; p-Tol, -10.6 +/- 0.4; p-CF3C6H4, -12.7 +/- 0.4; p-MeOC(6)H(4), -10.5 +/- 0.3. Electron-withdrawing para substituents on the aromatic aldehydes favor addition. Addition of nonanal is more favorable than addition of benzaldehydes, probably due to steric effects, particularly the close hydride-phenyl contact found in 2-Ph. 1 reacts with acyl chlorides (RC(O)Cl, R = octyl, Ph) rapidly to give Rh((PPr3)-Pr-i)(2)Cl-2[C(O)R] (3-R). 3-Ph possesses a square-pyramidal structure. The enthalpies of addition were also measured calorimetrically (R, Delta H/(kcal/mol)): octyl, -24.6 +/- 0.3; Ph, -21.7 +/- 0.3. Relative to the addition of acyl chlorides, the exothermicity of aldehyde addition is greater than would be expected on the basis of thermodynamic data for related late-transition-metal complexes.

  DOI：

  10.1021/om00010a065