| 207609-92-5

• CAS: 207609-92-5
• 化学式: C₁₂H₂₈O₈Pb₆
• 分子量: 1547.55
• InChiKey: BZJQODBTHRWTBV-ZYKHNVMDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二异丙醇铅 、 以 氘代甲苯 为溶剂， 生成
  参考文献：
  名称：

  Hydrolytic Synthesis of Lead Oxo Isopropoxides and Their Reaction with M(OⁱPr)₄ (M = Ti, Zr):  Comparisons and Contrasts

  摘要：

  Hydrolysis of [Pb((OPr2)-Pr-i] using selected stoichiometries yields [Pb4O(Pr-i)(6)] or [Pb6O4((OPr)-Pr-i)(4)], and stoichiometric [Pb((OPr)-Pr-i)(2)] converts [Pb6O4((OPr)-Pr-i)(4)] to [Pb4O((OPr)-Pr-i)(6)]. [Pb4O((OPr)-Pr-i)(6)] does not have the T-d structure of its (OBu)-Bu-i analogue. Reaction of electrophilic M((OPr)-Pr-i)(4) (M = Ti or Zr) with Pb4O((OPr)-Pr-i)(6) yields Pb3MO((OPr)-Pr-i)(8), by "displacement" of [Pb((OPr)-Pr-i)(2)]. However, reaction of the seemingly more accessible oxide in Pb6O4((OPr)-Pr-i)(4) with M((OPr)-Pr-i)(4) gives Pb3MO((OPr)-Pr-i)(8), together with other metal oxo alkoxides.

  DOI：

  10.1021/ic970709f
• 作为产物：
  描述：

  lead(II) bis(trimethylsilyl)amide 、 异丙醇 、 氧-17原子 以 四氢呋喃 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Hydrolytic Synthesis of Lead Oxo Isopropoxides and Their Reaction with M(OⁱPr)₄ (M = Ti, Zr):  Comparisons and Contrasts

  摘要：

  Hydrolysis of [Pb((OPr2)-Pr-i] using selected stoichiometries yields [Pb4O(Pr-i)(6)] or [Pb6O4((OPr)-Pr-i)(4)], and stoichiometric [Pb((OPr)-Pr-i)(2)] converts [Pb6O4((OPr)-Pr-i)(4)] to [Pb4O((OPr)-Pr-i)(6)]. [Pb4O((OPr)-Pr-i)(6)] does not have the T-d structure of its (OBu)-Bu-i analogue. Reaction of electrophilic M((OPr)-Pr-i)(4) (M = Ti or Zr) with Pb4O((OPr)-Pr-i)(6) yields Pb3MO((OPr)-Pr-i)(8), by "displacement" of [Pb((OPr)-Pr-i)(2)]. However, reaction of the seemingly more accessible oxide in Pb6O4((OPr)-Pr-i)(4) with M((OPr)-Pr-i)(4) gives Pb3MO((OPr)-Pr-i)(8), together with other metal oxo alkoxides.

  DOI：

  10.1021/ic970709f