| 23575-27-1

• CAS: 23575-27-1
• 化学式: C₁₄H₂₁ClCoN₅O₄
• 分子量: 417.798
• InChiKey: RCEJZEBGHCYMHB-DVTASQICSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 四苯硼钠 、 丙烯腈 以 甲醇 、 水 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  具有特别弱的给电子烷基的有机钴复合物。B12模型中结构与NMR光谱之间关系的扩展和定量

  摘要：

  DOI：

  10.1021/om00141a002
• 作为产物：
  描述：

  苯胺 、 [Co(dimethylglyoxime)2Cl2] 以 甲醇 为溶剂， 反应 1.0h， 以63%的产率得到
  参考文献：
  名称：

  Proton reduction using cobalt glyoximes with isothiocyanate and aniline axial ligands

  摘要：

  Cobaloxime model complexes containing aniline derivatives and isothiocyanate as the axial ligands Co(dmgH)(2)XY (dmgH = dimethylglyoxime, X = NCS, Cl and Y = aniline, pyridine) have been synthesized and used as proton reduction catalysts. Using acetic acid as the proton source in acetonitrile, cyclic voltammetry studies have shown that these complexes are comparable to the well-known Co(dmgH)(2)(pyridine)CI complex as a potent catalyst in terms of the overpotential and catalytic efficiency of proton reduction. In particular, we have shown that aniline derivatives can be used as possible pyridine alternatives in cobaloximes in our continuing search for an even more efficient proton reduction catalyst. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2015.04.030

文献信息

• Anhydrous trans-(Aniline)chlorobis(dimethylglyoximato)cobalt(III)
  作者：X. Solans、M. Font-Bardia、C. López、S. Alvarez

  DOI：10.1107/s0108270195009644

  日期：1996.1.15

  The crystal structure of anhydrous trans-(aniline)-chlorobis[dimethylglyoximato(1-)]cobalt(III), [CoCl-(C4H7N2O2)(2)(C6H7N)], has been determined. The Co ion shows distorted octahedral coordination with the N atoms of the dimethylglyoximato ligands in the equatorial sites and the N atom of aniline and the Cl atom in the apical sites. From the values of the Co-N distances and the N-Co-N angles it is deduced that both equatorial ligands are dimethylglyoximato(1-), while in the previously determined dihydrated compound the protonation sites are such as to give a (dimethylglyoxime) [dimethylglyoximato(2-)]cobalt complex.