N,N'-bisamideazophenylferrocene | 1422262-79-0

• 英文名称: N,N'-bisamideazophenylferrocene
• CAS: 1422262-79-0
• 化学式: C₃₆H₂₈FeN₆O₂
• 分子量: 632.504
• InChiKey: JAQOIDFJCFYBEV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,1'-ferrocenyldicarbonyl chloride 、 对氮蒽蓝 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 10.0h， 以67.4%的产率得到N,N'-bisamideazophenylferrocene
  参考文献：
  名称：

  Synthesis of novel colorimetric probe molecules and their application in anion recognition based on strong hydrogen bond

  摘要：

  A novel pair of ferrocene-containing azobenzene-based probe molecules, which behave as a selective probe for sensing fluoride and dihydrogen phosphate in colorimetric systems (even by naked eye), were designed. The probe 2 (N,N'-bisamideazophenyl-ferrocene) showed a high selectivity toward F- and H2PO4- with a color change from yellow to salmon pink without any interference from other ions. Meanwhile, the probe 1 (4-amideferrocenylazobenzene) showed only high selectivity for F- with a color change from yellow to salmon pink without any interference from other ions. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.12.012