[(n-Bu)4N]3[MoW5O19] | 81193-95-5

• 英文名称: [(n-Bu)4N]3[MoW5O19]
• CAS: 81193-95-5
• 化学式: 3C₁₆H₃₆N*MoO₁₉W₅
• 分子量: 2046.58
• InChiKey: JBMXIMDNULPILV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  4,4'-联吡啶 、 copper(II) choride dihydrate 、 [(n-Bu)4N]3[MoW5O19] 在 NH₄Cl 、 HCl 作用下， 以 水 为溶剂， 以33.6%的产率得到[(bipy)6Cu6Cl3(MoW5O19)]
  参考文献：
  名称：

  Polyoxometalate-based eight-connected self-catenated network and fivefold interpenetrating framework

  摘要：

  Two entangled compounds [(bpy)(6)(Cu6Cl3)-Cl-I((MoW5O19)-W-v)] (1) and [(bpy)(7)(Cu7Cl2)-Cl-I(BW12O40)]center dot H2O (2) (bpy=4,4'-bipyridine), have been successfully synthesized under hydrothermal conditions and characterized by element analysis, IR spectroscopy, thermal gravimetric analysis, X-ray photoelectron spectroscopy, and single crystal X-ray diffraction analyses. Compound I represents the first eight-connected self-penetrating network constructed from cuprous chloride clusters [Cu6Cl3] and Lindquist-type polyoxoanions. Compound 2 exhibits an interesting fivefold interpenetrating network consisting of Keggin polyoxoanions and Cu+-metal-organic Framework. Crystal data of the two compounds are following: 1, triclinic, P1, a=11.502(2)angstrom, b=13.069(3)angstrom, c=13.296(3)angstrom, alpha=90.55(3)degrees, beta=113.74(3)degrees, gamma=110.48(3)degrees, Z=1; 2, triclinic, P1, a=12.341(3)angstrom, b=13.119(3)angstrom, c=15.367(3)angstrom, alpha=99.12(3)degrees, beta = 90.53(3)degrees, gamma = 104.49(3)degrees, Z = 1. Crown Copyright (C) 2009 Published by Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2009.10.016
• 作为产物：
  描述：

  (Bu4N)2(MoW5O19) 、 tetrabutylammonium tetrafluoroborate 以 N,N-二甲基甲酰胺 为溶剂， 生成 [(n-Bu)4N]3[MoW5O19] 、
  参考文献：
  名称：

  Electron delocalization in mixed-valence molybdenum polyanions

  摘要：

  DOI：

  10.1021/ja00375a044

文献信息

• A new synthetic route to Lindqvist type clusters [(n-Bu4N)x][M′M5O19] [when x = 2, M′ = M = Mo or W; x = 3, M′ = Mo, M = W] from metal carbonyl precursors [(CO)5ML] [M = Mo, W; L= CO, C(OMe)(Me)]
  作者：Arunabha Thakur、Amarnath Chakraborty、V. Ramkumar、Sundargopal Ghosh

  DOI：10.1039/b908348k

  日期：——

  Fischer carbene complexes, [(CO)5M=C(OMe)Me] (M = Mo, W) in yields of 73, 77 and 71% respectively. All the clusters have been characterized by IR, 1H and 13C NMR spectra, and crystal structure determinations. Additionally, the composition of 9 has also been supported by mass spectrometry (MALDI-TOF), inductively coupled plasma (ICP) and energy-dispersive X-ray (EDX) analysis. This novel and mild route

  两个完全氧化的[（n-Bu4N）2] [Mo6O19]，7和[（n-Bu4N）2] [W6O19]，8和一个混合金属，化合价一个电子被还原[[n-Bu4N）3]。 [MoW5O19]在双相反应条件下从VI族金属羰基化合物或菲舍尔卡宾配合物合成了9个簇，[（CO）5M = C（OMe）Me]（M = Mo，W）的收率分别为73、77和71 ％ 分别。所有团簇均通过IR，1H和13C NMR光谱以及晶体结构测定来表征。此外，质谱仪（MALDI-TOF），电感耦合等离子体（ICP）和能量色散X射线（EDX）分析也支持了9的组成。这种新颖而温和的路线比Lindqvist型混合价混合金属多金属氧酸盐簇的早期合成方法提供了明显的改进。