| 1042334-04-2

• CAS: 1042334-04-2
• 化学式: C₂₃H₁₇MoO₅PS₂
• 分子量: 564.431
• InChiKey: HTGRWSHSKHREJC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 氘代氯仿 为溶剂， 生成
  参考文献：
  名称：

  Dithiafulvenylphosphine as P- and P,S-ligand towards metal carbonyl fragments

  摘要：

  The ability of the dithiafulvenylphosphine ( P-DTF) to react as a monodentate ( P) or a bidentate ( P, S) ligand with metal carbonyl complexes such as Mo(CO)(6) and MnBr(CO)(5) is presented. A series of metal carbonyl complexes are synthesised and characterised by IR, H-1 NMR and P-31 NMR spectroscopy. X-ray crystallographic analyses on the Mo( CO)(5)(P-DTF) and Mo(CO)(4)( P, S-DTF) complexes are reported together with the structural investigations on the dithiafulvenes precursors. The electrochemical properties of the various complexes investigated by cyclic voltammetry are discussed. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.04.011
• 作为产物：
  描述：

  molybdenum hexacarbonyl 、 (4,5-Dimethyl-[1,3]dithiol-2-ylidenemethyl)-diphenyl-phosphane 以 萘烷 为溶剂， 以44%的产率得到
  参考文献：
  名称：

  Dithiafulvenylphosphine as P- and P,S-ligand towards metal carbonyl fragments

  摘要：

  The ability of the dithiafulvenylphosphine ( P-DTF) to react as a monodentate ( P) or a bidentate ( P, S) ligand with metal carbonyl complexes such as Mo(CO)(6) and MnBr(CO)(5) is presented. A series of metal carbonyl complexes are synthesised and characterised by IR, H-1 NMR and P-31 NMR spectroscopy. X-ray crystallographic analyses on the Mo( CO)(5)(P-DTF) and Mo(CO)(4)( P, S-DTF) complexes are reported together with the structural investigations on the dithiafulvenes precursors. The electrochemical properties of the various complexes investigated by cyclic voltammetry are discussed. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.04.011