Synthesis of Bis( <sup>5</sup>-cyclopentadienyldicarbonyliron)stannane Dichloride by Direct Oxidation of Tin and Reaction of This Compound and Its Analogs with Magnesium
作者:S. V. Maslennikov、M. V. Tsarev、I. V. Spirina、A. V. Lado、V. P. Maslennikov、A. A. Usanov
DOI:10.1023/b:rugc.0000045872.42657.fd
日期:2004.7
A procedure was developed for preparing [Cp(CO)(2)Fe](2)SnCl2 by direct oxidation of tin with eta5-cyclopentadienyldicarbonyliron chloride in polar solvents. The reaction kinetics was studied, and its scheme was suggested. Products of the reaction of magnesium with compounds R2SnCl2 [R = CP(CO)(3)Mo, Cp(CO)(3)W, Cp(CO)(2)Fe] were identified. The reaction mechanism was discussed.