[Mn2(1,10-phenanthroline)2(μ-O)(μ-chloroacetate)2(NO3)(H2O)](ClO4) | 891184-01-3

• 英文名称: [Mn2(1,10-phenanthroline)2(μ-O)(μ-chloroacetate)2(NO3)(H2O)](ClO4)
• 英文别名: [Mn2(phen)2(μ-O)(μ-OOCCH2Cl)2(NO3)(H2O)](ClO4)
• CAS: 891184-01-3
• 化学式: C₂₈H₂₂Cl₂Mn₂N₅O₉*ClO₄
• 分子量: 852.743
• InChiKey: JUFKLHFEFXLUIN-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氯乙酸 、 sodium perchlorate monohydrate 、 1,10-菲罗啉 、 manganese(II) perchlorate hexahydrate 、 ammonium cerium (IV) nitrate 在 triethylamine 作用下， 以 乙腈 为溶剂， 生成 [Mn2(1,10-phenanthroline)2(μ-O)(μ-chloroacetate)2(NO3)(H2O)](ClO4)
  参考文献：
  名称：

  Binuclear manganese(III) complexes with carboxylate bridges: Synthesis, structure, electrochemistry and magnetic properties

  摘要：

  A series of mu-oxo, mu-carboxylato binuclear manganese(III) complexes derived from bipy, phen and different carboxylate ligands have been prepared and characterized by IR and UV-vis spectroscopies, cyclic voltammetry, magnetic susceptibility and the X-ray crystallography. The electronic spectra of all the complexes show very similar features consisting of two absorptions in the visible region, one high intensity LMCT band and two intra-ligand transitions in the UV region. The cyclic voltammograms of the complexes exhibit four steps in most cases, each consisting of a one-electron transfer reaction. These probably correspond to Mn-2(III) <-> (MnMnIII)-Mn-IV <-> Mn-2(IV) oxidation and Mn-2(III) <-> (MnMnII)-Mn-III <-> Mn-2(OO) reduction processes. The structure of complex 2 has been determined by the X-ray crystallography and consists of a binuclear [Mn-2(bipy)(2)(mu-O)(mu-OOCR)(2)(NO3)(H2O)](+) cation (R = CH2Cl) with a ClO4- anion. Low temperature magnetic susceptibility measurements show that there is a weak ferromagnetic interaction in 1 (R = Ph) (J = +0.43 cm(-1)) and a weak antiferromagnetic interaction between the metal centers in 2 (R = CH2Cl) (J = -0.15 cm(-1)). (C) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.11.022