6-hydroxy-nido-decaborane | 98514-25-1

• 英文名称: 6-hydroxy-nido-decaborane
• 英文别名: 6-(OH)B10H13
• CAS: 98514-25-1
• 化学式: B₁₀H₁₄O
• 分子量: 138.221
• InChiKey: BRCIOKLMAUMUQG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  6-hydroxy-nido-decaborane 以 苯 为溶剂， 以60%的产率得到6,6'-bis(nido-decaboranyl) oxide
  参考文献：
  名称：

  Dehydration of (H3O)2B10H10: An improved preparation of icosaborane oxide, (B10H13)2O

  摘要：

  DOI：

  10.1016/s0020-1693(00)85221-4
• 作为产物：
  描述：

  bis(tetraethylammonium) decahydro-closo-decaborate 以 水 为溶剂， 生成 6-hydroxy-nido-decaborane
  参考文献：
  名称：

  Dehydration of (H3O)2B10H10: An improved preparation of icosaborane oxide, (B10H13)2O

  摘要：

  DOI：

  10.1016/s0020-1693(00)85221-4

文献信息

• Reactions of 6,6′-bis(nido-decaboranyl) oxide and 6-hydroxy-nido-decaborane with dihalogenobis(phosphine) complexes of nickel, palladium, and platinum, and some related chemistry; nuclear magnetic resonance investigations and the crystal and molecular structures of bis(dimethylphosphine)-di-µ-(2,3,4-η³-nido-hexaboranyl)-diplatinum(Pt–Pt), [Pt₂(µ-η³-B₆H₉)₂(PMe₂Ph)₂], and of 2,4-dichloro-1,1-bis(dimethylphenylphosphine)-closo-1-nickeladecaborane, [(PhMe₂P)₂NiB₉H₇Cl₂]
  作者：Norman N. Greenwood、Michael J. Hails、John D. Kennedy、Walter S. McDonald

  DOI：10.1039/dt9850000953

  日期：——

  arachno-palladaplatinaborane species and the first metallaborane of any kind to contain metals from two different periods in the Periodic Table. Treatment of (2) with base followed by cis-[ PdCl2(PMe2Ph)2] gives the 15-vertex trimetallaborane cluster compound [ Pt2(µ-η3- B6H9)(µ-η3- B6H8-η2- PtH (PMe2Ph)2})(PMe2Ph)2]. The 1H, 11B, and 31P n.m.r. behaviour of these compounds have been investigated in detail using both

  经过改进的制备和分离6,6'-（B 10 H 13）2 O的步骤也导致了新化合物6-B 10 H 13 OH的分离，该化合物的特征是11 B和1 H核磁共振和质谱。比较了这两种相关的氧硼烷的结构和化学性质。6,6'-（B 10 H 13）2 O或6-B 10 H 13 OH与顺式-[Pt 2 Cl 2 L 2 ]（L = PMe 2 Ph或PPh 3的反应）给出三种铂硼烷，蛛网菌-[L 2 PtB 8 H 12 ]（1），氨基-[L 2 PtB 10 H 12 ]，和[Pt 2（µ-η 3 -B 6 H 9）2 L 2 ]（2）。（2）（L = PMe 2 Ph）的黄针是单斜的，空间群P 2 1 / c，a = 1 014.0（2），b = 586.8（2），c= 2 316.9（6）PM，β= 91.66（2）°，Z = 2且分子结构是中心对称的14顶点芳族-二铂硼烷，其中两个B 6 H
• New method of synthesis of 6-hydroxy-nido-decaborane 6-(OH)B10H13 by cage opening of closo-[B10H10]2−
  作者：Daoud Naoufal、Maher Kodeih、David Cornu、Philippe Miele

  DOI：10.1016/j.jorganchem.2005.01.041

  日期：2005.6

  6-hydroxy-nido-decaborane 6-(OH)B10H13 was prepared by opening the cage [B10H10](2-) in strong acidic medium. The reaction must be carried out in the presence of an inert solvent such as hexane. 6-(OH)B10H13 is obtained with a 30% yield and characterized by B-11 NMR and I.R. Boric acid was also detected. Attempts to reproduce the opening of the [B10H10](2-) cage in basic or neutral media have been unsuccessful. (c) 2005 Elsevier B.V. All rights reserved.