| 1431325-73-3

• CAS: 1431325-73-3
• 化学式: C₇₃H₆₃ClFeN₉O₃
• 分子量: 1205.66
• InChiKey: HFOQWBGLZJFCPY-ACOYPIRTSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 copper diacetate 以 乙腈 为溶剂， 反应 0.17h， 以98%的产率得到
  参考文献：
  名称：

  CO and O2 binding studies of new model complexes for CcO

  摘要：

  A very efficient, simple synthesis of a porphyrin mimic for cytochrome c oxidase is presented. This complex contains a covalently attached copper binding site and a phenyl ring that mimics the Tyr part of the enzyme. Structural studies revealed that the copper binding tridentate ligand is situated on top of the porphyrin plane and the hydroxyl of the phenyl ring is oriented towards the center of the molecule. Moreover, Fe at the reduced form of the model is capable of binding CO, as confirmed by FT-IR and upon photolysis CO is bound to Cu site. Finally, electrochemical studies using rotating ring-disk electrode showed that the complexes reduce oxygen via two mechanisms (2e(-) and 4e(-)) and have low stability. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.01.050
• 作为产物：
  描述：

  N-(2-(20-(2-(2-(bis(2-(pyridin-2-yl)ethyl)amino)acetamido)phenyl)-5,15-dimesitylporphyrin-10-yl)phenyl)-2-hydroxybenzamide 、 iron(II) bromide 在 盐酸 作用下， 以 四氢呋喃 、 氯仿 为溶剂， 反应 12.0h， 以79%的产率得到
  参考文献：
  名称：

  CO and O2 binding studies of new model complexes for CcO

  摘要：

  A very efficient, simple synthesis of a porphyrin mimic for cytochrome c oxidase is presented. This complex contains a covalently attached copper binding site and a phenyl ring that mimics the Tyr part of the enzyme. Structural studies revealed that the copper binding tridentate ligand is situated on top of the porphyrin plane and the hydroxyl of the phenyl ring is oriented towards the center of the molecule. Moreover, Fe at the reduced form of the model is capable of binding CO, as confirmed by FT-IR and upon photolysis CO is bound to Cu site. Finally, electrochemical studies using rotating ring-disk electrode showed that the complexes reduce oxygen via two mechanisms (2e(-) and 4e(-)) and have low stability. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.01.050