(η6-benzene)Ru(saccharinate)2(H2O) | 1336889-61-2

• 英文名称: (η6-benzene)Ru(saccharinate)2(H2O)
• CAS: 1336889-61-2
• 化学式: C₂₀H₁₆N₂O₇RuS₂
• 分子量: 561.558
• InChiKey: HYQRPHJRAAWRSI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [RuCl2(benzene)]2 、 水 、 saccharin sodium salt 以 乙醇 、 水 为溶剂， 以74%的产率得到(η6-benzene)Ru(saccharinate)2(H2O)
  参考文献：
  名称：

  Arene ruthenium bis-saccharinato complexes: Synthesis, molecular structure and catalytic oxidation properties in aqueous solution

  摘要：

  Arene ruthenium complexes [(eta(6)-arene)Ru(sacc)(2)(OH2)] (arene - para-cymeme, benzene) containing an aqua and two saccharinato ligands have been synthesized from [(eta(6)-arene) RuCl2](2) and sodium saccharinate in a water-ethanol mixture (1:1). The aqua complex [(eta(6)-MeC6H4Pri)Ru(sacc)(2)(OH2)] reacts with acetonitrile to give the acetonitrile complex [(eta(6)-MeC6H4Pri)Ru(sacc)(2)(NCMe)]. The corresponding benzene derivative [(eta(6)-C6H6) Ru(sacc)(2)(NCMe)] was obtained from [(eta(6)-C6H6)RuCl2](2) and saccNa in an acetonitrile-methanol mixture (1:1). All new complexes show a piano-stool geometry with two monohapto nitrogen-bonded saccharinato ligands in addition to a H2O or MeCN ligand. All complexes of the type [(eta(6)-arene) Ru(sacc)(2)(OH2)] and [(eta(6)-arene) Ru(sacc)(2)(NCMe)] were found to catalyze the oxidation of secondary alcohols with tert-butyl hydroperoxide ((BuOOH)-O-t) to give the corresponding ketones in aqueous solution. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.06.033