1-Ph-2-Me-3,3-(PMe2Ph)2-3,1,2-PtC2B9H9 | 167173-03-7

• 英文名称: 1-Ph-2-Me-3,3-(PMe2Ph)2-3,1,2-PtC2B9H9
• CAS: 167173-03-7
• 化学式: C₂₅H₃₉B₉P₂Pt
• 分子量: 693.911
• InChiKey: XRZYGJAKTVHXNE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cis-[bis(dimethylphenylphosphane)dichlroplatinum(II)] 、 Tl2[7-Ph-8-Me-7,8-nido-C2B9H9] 以 二氯甲烷 为溶剂， 以51.2%的产率得到1-Ph-2-Me-3,3-(PMe2Ph)2-3,1,2-PtC2B9H9
  参考文献：
  名称：

  Enhanced slip distortions in 1-phenyl-2-methyldicarbaplatinaboranes. Conformational destabilisation in the isomerisation of 1-phenyldicarbaplatinaboranes

  摘要：

  The compounds Tl-2[7-Ph-8-Me-7,8-nido-C2B9H9], [C5H10NH2] [7-Ph-8-Me-7,8-nido-C2B9H10], 1-Ph-2-Me-3,3-L(2)-3,1,2-PtC2B9H9 [L = PMe(2)Ph, PEt(3), PPh(3) or P(C(6)H(4)Me-p)(3)] have been prepared and characterised. The platinum complexes were obtained from the reactions between Tl-2[7-Ph-8-Me-7,8-nido-C2B9H9] and the appropriate [PtCl2(PR(3))(2)] species. Crystallographic studies upon the compounds where L = PEt(3) and two crystalline modifications of that where L = PPh(3) afforded evidence of a substantial influence of intramolecular crowding upon the observed structures, so that the lateral slippage (Delta) of the metal fragment is significantly enhanced: Delta = 0.74 and 0.94 and 0.91 Angstrom respectively. These compounds do not isomerise under conditions which produce rearrangement in the corresponding (less-congested) derivatives of 1-phenylcarbaborane, consistent with the proposed conformational destabilisation in the latter system.

  DOI：

  10.1039/dt9950001755