| 162024-62-6

• CAS: 162024-62-6
• 化学式: AlCl₄*C₂₆H₃₇Cl₂MoP₂
• 分子量: 747.167
• InChiKey: STNRGRBAUMQKNK-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三氯化铝 、 以 二氯甲烷 为溶剂， 以62.5%的产率得到
  参考文献：
  名称：

  Instability of 15-electron derivatives. X-ray structure of Cp☆MoCl2(PMe2Ph)2 and [Cp☆MoCl2(PMe2Ph)2]AlCl4

  摘要：

  The complex Cp*MoCl2(PMe(2)Ph)(2) (Cp* = eta(5)C(5)Me(5)) has been obtained in good yields from Cp*MoCl4, PMe(2)Ph(2), and Na in the appropriate stoichiometric ratio, and it is also obtained by a ligand redistribution process after reduction of Cp*MoCl3-(PMe(2)Ph) with Na. This compound is oxidized by the CH2Cl2 solvent in the presence of AlCl3 to afford the salt [Cp*MoCl2-, (PMe(2)Ph)(2)]AlCl4. Both compounds have been characterized crystallographically and by H-1-NMR spectroscopy. The reasons for the instability of 15-electron Cp*MoCl(2)L complexes are discussed. The H-1-NMR resonance data for Cp*MoCl(2)L(2) (L = PMe(3), PMe(2)Ph) and [Cp*MoCl2(PMe(2)Ph)(2)](+) are also discussed.

  DOI：

  10.1016/0022-328x(94)00005-w