[(Re2(CO)9)2(μ-(1-(di-o-anisylphosphino)-3-(diphenylphosphino)propane)] | 866367-62-6

• 英文名称: [(Re2(CO)9)2(μ-(1-(di-o-anisylphosphino)-3-(diphenylphosphino)propane)]
• 英文别名: [Re2(CO)9(μ-(P(o-anisyl)2(CH2)3PPh2)Re2(CO)9]
• CAS: 866367-62-6
• 化学式: C₄₇H₃₀O₂₀P₂Re₄
• 分子量: 1721.52
• InChiKey: YAKJGVDTVMCBJC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  十羰基二铼 、 1-(di-o-anisylphosphino)-3-(diphenylphosphino)propane 在 Me₃NO*2H₂O 作用下， 以 四氢呋喃 为溶剂， 以9%的产率得到eq-[Re2(CO)9(η1-(1-(di-o-anisylphosphino)-3-(diphenylphosphino)propane)]
  参考文献：
  名称：

  Rhenium carbonyl complexes with monodentate-coordinated diphosphines: activation of terminal phosphino groups towards amine-oxide oxidation

  摘要：

  Terminal phosphino groups of [Re-2(CO)(9)(eta(1)-P-P)] (P-P = diphosphines) are activated towards oxidation by Me3NO. The respective reactions of MC3NO with [Re-2(CO)(9){eta(1)-P(o-anisyl)(2)(CH2)PPh2}], [Re-2(CO)(9){eta(1)-PPh2(CH2)(3)P(o-anisyl)(2)}] and [Re-2(CO)(9)(eta(1)-trans-PPh2CH=CHPPh2)] were studied to investigate the mechanism of this oxidation. The results are consistent with an intramolecular pathway involving a cyclic intermediate, without exchange of the coordinated and terminal phosphino groups. A mechanism which involves an interaction of the terminal phosphino group with a carbonyl ligand is proposed. In sharp contrast to eq-[Re-2(CO)(9)(eta(1)-P-P)] (P-P = Ph2P(CH2)(n)PPh2, n = 1-6), eq-[Re-2(CO)(9)(eta(1)-trans-PPh2CH=CHPPh2)] appears to be indefinitely stable towards equatorial -> axial isomerization at room temperature, thus, allowing its crystal structure to be determined. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.05.010