chloro-bis[2-[(dimethylamino)methyl]phenyl]aluminium | 164264-44-2

• 英文名称: chloro-bis[2-[(dimethylamino)methyl]phenyl]aluminium
• CAS: 164264-44-2
• 化学式: C₁₈H₂₄AlClN₂
• 分子量: 330.836
• InChiKey: TVDYBLNGLKGTDP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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反应信息

• 作为反应物：
  描述：

  chloro-bis[2-[(dimethylamino)methyl]phenyl]aluminium 、 sodium azide 以 甲苯 为溶剂， 以76%的产率得到azidobis(2-[(dimethylamino)methyl]phenyl)aluminium
  参考文献：
  名称：

  Syntheses and Structures of Intramolecularly Coordinated Azidoalanes

  摘要：

  The four intramolecularly coordinated azidoalanes R2Al(N-3) and RAltBu(N-3) (R = (CH2)(3)NMe2 (1b, 3b), 2-(Me2NCH2)C6H4 (2b, 4b)) were synthesized by reaction of the corresponding aluminum chlorides (1a-4a) with an excess of dry sodium azide in refluxing toluene or toluene/THF. The structures of the products were deduced from H-1, C-13, and Al-27 NMR spectra and were confirmed by X-ray structural determinations of la, Ib, and 2b. The compounds of type 1 and 2 contain pentacoordinated Al atoms, whereas the alanes of type 3 and 4 show tetracoordination of the central Al atoms.

  DOI：

  10.1021/om9706875
• 作为产物：
  描述：

  三氯化铝 、 2-(N,N-dimethylaminomethyl)phenyllithium 以 乙醚 为溶剂， 以78%的产率得到chloro-bis[2-[(dimethylamino)methyl]phenyl]aluminium
  参考文献：
  名称：

  Mueller, Jens; Englert, Ulli, Chemische Berichte, 1995, vol. 128, # 5, p. 493 - 498

  摘要：

  DOI：

文献信息

• Quest for Active Species in Al/B-Catalyzed CO₂ Hydrosilylation
  作者：Sheetal Kathayat Bisht、Deepti Sharma、Ramkumar Kannan、Thayalan Rajeshkumar、Laurent Maron、Ajay Venugopal

  DOI：10.1021/acs.inorgchem.3c02771

  日期：2023.11.13

  We demonstrate the catalytic role of aluminum and boron centers in aluminum borohydride [(2-Me2CH2C6H4)(C6H5)Al(μ-H)2B(C6H5)2] (6) during carbon dioxide (CO2) hydrosilylation. Preliminary investigations into CO2 reduction using [(2-Me2NCH2C6H4)(H)Al(μ-H)]2 (1) and [Ph3C][B(3,5-C6H3Cl2)4] (2) in the presence of Et3SiH and PhSiH3 resulted in CH2(OSiR3)2 and CH3OSiR3, which serve as formaldehyde and methanol

  我们证明了铝和硼中心在硼氢化铝中的催化作用 [(2-Me 2 CH 2 C 6 H 4 )(C 6 H 5 )Al(μ-H) 2 B(C 6 H 5 ) 2 ] ( 6）在二氧化碳（CO 2）氢化硅烷化过程中。使用[(2-Me 2 NCH 2 C 6 H 4 )(H)Al(μ-H)] 2 ( 1 )和[Ph 3 C][B(3,5-C 6 H)还原CO 2的初步研究3 Cl 2 ) 4 ] ( 2 )在Et 3 SiH和PhSiH 3存在下产生CH 2 (OSiR 3 ) 2和CH 3 OSiR 3，它们分别充当甲醛和甲醇替代物。为了鉴定活性催化物质，三种化合物：B(3,5-C 6 H 3 Cl 2 ) 3 ( 3 )、[(2-Me 2 NCH 2 C 6 H 4 )(3,5-C 6 H 3 Cl 2 )Al(μ-H) 2 B(3,5-C 6 H 3 Cl 2 ) 2 ] ( 4 ) 和 [(2-Me