cesium trifluorocobaltate(II) | 27858-43-1

• 英文名称: cesium trifluorocobaltate(II)
• CAS: 27858-43-1
• 化学式: CoF₃*Cs
• 分子量: 248.894
• InChiKey: ZUIBCGPOKOQKOV-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -1.74
• 重原子数：
  5.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  钴 、 cesium fluoride 以 氢氟酸 为溶剂， 以82%的产率得到cesium trifluorocobaltate(II)
  参考文献：
  名称：

  Chakravorti; Subrahmanyam; Bandyopadhyay, Journal of the Indian Chemical Society, 1990, vol. 67, # 10, p. 835 - 836

  摘要：

  DOI：

文献信息

• Electrosynthesis of transition metal fluoro complexes by the dissolution of a sacrificial metal anode
  作者：M.C. Chakravorti、Gampa.V.B. Subrahmanyam、D. Bandyopadhyay

  DOI：10.1016/s0277-5387(00)81335-2

  日期：1991.1

  A general method for the electrosynthesis of anionic fluoro complexes of transition metals has been developed by the oxidation of sacrificial metal anodes in 20% HF medium at room temperature and at an applied potential of 2-8 V. Some mixed-valent complexes, e.g. Fe2F5.2H2O and Fe2F5.7H2O, have also been obtained by the same method. K2[MnF5].H2O was obtained by subsequent electrolytic oxidation of the Mn(II) fluoro complex obtained in situ in the first step. The method is rapid and gives a good yield with high purity.