1-(3-aminophenyl)-2-phenyl-1,2-dicarba-closo-dodecaborane | 490040-99-8

• 英文名称: 1-(3-aminophenyl)-2-phenyl-1,2-dicarba-closo-dodecaborane
• CAS: 490040-99-8
• 化学式: C₁₄H₂₁B₁₀N
• 分子量: 311.437
• InChiKey: JTUPXXLUTNHGIH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  甲酸 、 1-(3-aminophenyl)-2-phenyl-1,2-dicarba-closo-dodecaborane 在 Ac₂O 作用下， 以 四氢呋喃 为溶剂， 以83.5%的产率得到1-(3-formamidophenyl)-2-phenyl-1,2-dicarba-closo-dodecaborane
  参考文献：
  名称：

  Molecular construction based on icosahedral carboranes and aromatic N,N′-dimethylurea groups. Aromatic layered molecules and a transition metal complex

  摘要：

  cis-Preference of N-methyl aromatic ureas in combination with regulation of the C-substituent on an o-carborane cage is applicable to construct structurally unique macromolecules. Aromatic ureas with multilayer structure (5-12) and an aromatic urea containing an intramolecular nido-carborane-cobalt complex (13) were synthesized and their structures were determined by X-ray crystallography. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01322-0
• 作为产物：
  描述：

  癸硼烷 、 3-(苯基乙炔基)苯胺 在 MeCN 作用下， 以 苯 为溶剂， 以28%的产率得到1-(3-aminophenyl)-2-phenyl-1,2-dicarba-closo-dodecaborane
  参考文献：
  名称：

  Molecular construction based on icosahedral carboranes and aromatic N,N′-dimethylurea groups. Aromatic layered molecules and a transition metal complex

  摘要：

  cis-Preference of N-methyl aromatic ureas in combination with regulation of the C-substituent on an o-carborane cage is applicable to construct structurally unique macromolecules. Aromatic ureas with multilayer structure (5-12) and an aromatic urea containing an intramolecular nido-carborane-cobalt complex (13) were synthesized and their structures were determined by X-ray crystallography. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01322-0