[InH2Br(quinuclidine)2] | 861636-63-7

• 英文名称: [InH2Br(quinuclidine)2]
• CAS: 861636-63-7
• 化学式: C₁₄H₂₈BrInN₂
• 分子量: 419.114
• InChiKey: JPGXPRKUSBICKM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [InH2Br(quinuclidine)2] 以 neat (no solvent, solid phase) 为溶剂， 生成 indium
  参考文献：
  名称：

  Controlled Decomposition of an Indium Trihydride Adduct:  Synthesis and Characterization of the First Mixed-Oxidation-State Indium Sub-halide Complex Anion, [In₅Br₈(quinuclidine)₄]^-

  摘要：

  The first example of a compound containing a mixed-oxidation-state indium sub-halide complex anion, [ln(5)Br(8)(quinuclidine)(4)](-), has been accessed by the controlled decomposition of an indium trihydride adduct, [InH3(quinuclidine)], in the presence of LiBr. An intermediate in this reaction, [InH2Br(quinuclidine)2], has been isolated and suggests that its mechanism involves hydride-bromide exchange, reductive dehydrogenation, and disproportionation process.

  DOI：

  10.1021/ic050415r
• 作为产物：
  描述：

  lithium tetrahydridoindanate 、 奎宁环盐酸盐 、 lithium bromide 以 乙醚 为溶剂， 以24%的产率得到[InH2Br(quinuclidine)2]
  参考文献：
  名称：

  Controlled Decomposition of an Indium Trihydride Adduct:  Synthesis and Characterization of the First Mixed-Oxidation-State Indium Sub-halide Complex Anion, [In₅Br₈(quinuclidine)₄]^-

  摘要：

  The first example of a compound containing a mixed-oxidation-state indium sub-halide complex anion, [ln(5)Br(8)(quinuclidine)(4)](-), has been accessed by the controlled decomposition of an indium trihydride adduct, [InH3(quinuclidine)], in the presence of LiBr. An intermediate in this reaction, [InH2Br(quinuclidine)2], has been isolated and suggests that its mechanism involves hydride-bromide exchange, reductive dehydrogenation, and disproportionation process.

  DOI：

  10.1021/ic050415r