methyluranocene | 124020-89-9

• 英文名称: methyluranocene
• CAS: 124020-89-9
• 化学式: C₁₈H₂₀U
• 分子量: 474.386
• InChiKey: SVGQNZYHYWASLA-QHRBYHCESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  methyluranocene 在 氢化钾 作用下， 以 四氢呋喃 为溶剂， 生成 potassium bis(methyl{8}annulenediyl)uranate(III)*99 diglyme
  参考文献：
  名称：

  Eisenberg, David C.; Streitwieser, Andrew; Kot, Wing K., Inorganic Chemistry, 1990, vol. 29, # 1, p. 10 - 14

  摘要：

  DOI：
• 作为产物：
  描述：

  、 氯化铀 以 四氢呋喃 为溶剂， 以5%的产率得到methyluranocene
  参考文献：
  名称：

  Spiegl, A. W., Diss. Erlagen (1978)

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: U: SVol.E2, 2, page 113 - 176
  作者：

  DOI：——

  日期：——
• Structures of organo-f-element compounds differing in the oxidation state of the central metal: crystal structures of bis([8]annulene) complexes of cerium(IV), ytterbium(III), and uranium(III)
  作者：Thomas R. Boussie、David C. Eisenberg、John Rigsbee、Andrew Streitwieser、Alan Zalkin

  DOI：10.1021/om00052a044

  日期：1991.6

  Crystal structures of bis(methyl[8]annulene)cerium(IV) (5), [(diethylene glycol dimethyl ether)potassium] [bis([8]annulene)ytterbate(III)] (14), and [(diethylene glycol dimethyl ether)potassium] [bis(methyl[8]-annulene)uranate(III)] (12) are reported. These include the first structures of an organocerium(IV) compound and of a reduced uranocene. Crystals of 5 are orthorhombic, P2(1)2(1)2(1), with a = 11.690 (3) angstrom, b = 14.315 (3) angstrom, c = 8.977 (2) angstrom, Z = 4, and R(F) = 2.9%. Crystals of 14 are also orthorhombic, Pbca, with a = 16.611 (4) angstrom, b = 14.219 (5), angstrom, c = 9.257 (4) angstrom, Z = 4, and R(F) = 3.6%. Crystals of 12 are monoclinic, P2(1)/c, with a = 13.833 (4) angstrom, b = 9.989 (3) angstrom, c = 17.581 (3) angstrom, beta = 95.87 (3)degrees, Z = 4, and R(F) = 3.8%. These structures are compared to the previously reported structures of [(diethylene glycol dimethyl ether)potassium] [bis([8]annulene)cerate(III)] (13), bis[(dimethoxyethane)potassium] [bis([8]annulene)ytterbate(II)] (15), and uranocene (1). A comparison of the structural parameters of several additional [8]annulene metal complexes is also presented. The effect of coordination number on metal ligand distances in ionic complexes is discussed in terms of electrostatic interactions among the ligands.