{Nb(η-C6H5CH3)(tmps)H} | 125893-29-0

• 英文名称: {Nb(η-C6H5CH3)(tmps)H}
• CAS: 125893-29-0
• 化学式: C₁₇H₃₆NbP₃Si
• 分子量: 454.386
• InChiKey: BBXNVJNJYJFXBR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  {Nb(η-C6H5CH3)(tmps)} 、 氢化钾 以 四氢呋喃 为溶剂， 以45%的产率得到{Nb(η-C6H5CH3)(tmps)H}
  参考文献：
  名称：

  Synthesis, structure and reactivity of new low-valent mono(η-arene)niobium compounds

  摘要：

  The new compounds [Nb(eta-C6H5Me)(PMe3)3R] (R = H or SiMe3), [Nb(eta-C6H5Me)(tmps)], dagger [Nb(eta-C6H5Me)(tmps)H] [tmps = MeSi(CH2PMe2)3], [Nb(eta-C6H5Me)(eta-C5H5)(PMe3)], [Nb(eta-C6H5Me)(eta-5-C9H7)(PMe3)], [Nb(eta-5-C9H7)(CO)3(PMe3)], dagger [Nb(eta-C7H7)(eta-4-C7H8)(PMe3)], [Nb(CO)3(PMe3)4][Nb(CO)5(PMe3)], dagger [Nb(eta-C7H7)(CO)2(PMe3)], [Nb(eta-C6H5Me)2X] (X = Br, I, Me, Ph or CH2Ph), [{Nb(eta-C6H5Me)(mu-SR)2}2] (R = CH2Ph, Me or Bu) and [{Mo(eta-C6H5Me)(mu-SePh)2}2][PF6]2 have been prepared (dagger indicates the crystal structure has been determined). Evidence for the anions [Nb(eta-C6H5Me)(PMe3)3]- and [Nb(eta-C6H5Me)(tmps)]- is presented.

  DOI：

  10.1039/dt9910001705