[(η5-Ph2P(O)C5H4)2Co]PF6 | 761405-20-3

• 英文名称: [(η5-Ph2P(O)C5H4)2Co]PF6
• CAS: 761405-20-3
• 化学式: C₃₄H₂₈CoO₂P₂*F₆P
• 分子量: 734.5
• InChiKey: PLZCVTBBFMEHBQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,1'-bis(diphenylphosphino)cobaltocenium hexafluorophosphate 、 双氧水 以 四氢呋喃 、 水 为溶剂， 以87%的产率得到[(η5-Ph2P(O)C5H4)2Co]PF6
  参考文献：
  名称：

  1,1'-双（膦基）钴铯化合物的合成与电化学

  摘要：

  1,1'-双（二苯基膦基）六氟磷酸钴铈（[dppc] [PF 6 ]），1,1'-双（二环己基膦基）六氟磷酸钴铯（[dcpc] [PF 6 ]），1,1'-的电化学用二氯甲烷和四丁基铵在二氯甲烷中检测了双（二异丙基膦基）六氟磷酸钴铈（[dippc] [PF 6 ]）和1-（二叔丁基膦基）六氟磷酸钴铈（[1-dtbpc] [PF 6 ]）。六氟磷酸盐作为支持电解质。在更负的电势下观察到可逆的还原波，然后是不可逆的波。十个新的膦硫硫基（[dppcS 2 ] [PF 6 ]，[dcpcS 2 ] [PF 6 ]，[dippcS 2] [PF 6 ]，[1-dtbpcS] [PF 6 ]和1,1'-双（二环己基膦硫基硫基）二茂铁）和膦硒烯酰基衍生物（[dppcSe 2 ] [PF 6 ]，[dcpcSe 2 ] [PF 6 ]，制备并表征了[dippcSe 2 ] [PF 6 ]，[1-dtbpcSe]

  DOI：

  10.1016/j.jorganchem.2011.09.004

文献信息

• Synthetic and Structural Studies on the Transition-Metal Fullerene Complexes (η²-C₆₀)M[(η⁵-Ph₂PC₅H₄)₂Ru] and (η²-C₆₀)M[(η⁵-Ph₂PC₅H₄)₂Co]⁺(PF₆)^- (M = Pd, Pt) and the Related Compound {[<i>η</i>⁵-Ph₂P(O)C₅H₄]₂Co}⁺(PF₆)^-
  作者：Li-Cheng Song、Guang-Ao Yu、Fu-Hai Su、Qing-Mei Hu

  DOI：10.1021/om049667a

  日期：2004.8.1

  A toluene solution Of C-60 reacted with an equimolar quantity of M(dba)(2) (M = Pd, Pt; dba = dibenzylideneacetone) and (eta(5)-Ph2PC5H4)(2)Ru or with M(PPh3)(4) and (eta(5)-Ph2PC5H4)(2)Ru at room temperature to give the dinuclear transition-metal fullerene complexes (eta(2)-C-60)M [(eta(5)-Ph2PC5H4)(2)Ru] (1, M = Pd; 2, M = Pt), whereas the o-dichlorobenzene solution of C-60 reacted with an equimolar amount of M(dba)(2) and [(eta(5)-Ph2PC5H4)(2)Co](+)(PF6)(-) or with M(PPh3)(4) and [(eta(5)-Ph2PC5H4)(2)Co](+)(PF6)(-) under similar conditions to afford the dinuclear transition-metal fullerene complexes (eta(2)-C-60)M[(eta(5)-Ph2PC5H4)(2)Co](+)(PF6)(-) (3, M = Pd; 4, M = Pt). In addition, the related complex [eta(5)-Ph2P(O)C5H4](2)Co}(+)(PF6)(-) (5) was prepared by oxidation of [(eta(5)-Ph-2-PC5H4)(2)Co](+)(PF6)(-) with an excess amount of aqueous peracetic acid in acetone at room temperature. While 1-4 are the first examples of neutral and cationic dinuclear M/Ru and M/Co (M = Pd, Pt) fullerene complexes, 5 is the first organocobalt Cp complex containing a phosphoryl substituent. All products 1-5 have been fully characterized by elemental analysis, spectroscopy, and X-ray crystal diffraction techniques and, for 1 and 2, by cyclic voltammetry.