| 221040-78-4

• CAS: 221040-78-4
• 化学式: C₂₉H₂₇BrFeNPPd
• 分子量: 662.685
• InChiKey: CGDKFPJNDCNCCY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 三苯基膦 以 氘代氯仿 为溶剂， 生成
  参考文献：
  名称：

  Palladium (II) compounds containing mono- and bidentate primary ferrocenylamines. a study of the cyclopalladation of: [ (η5-C5H5)Fe{ (η5-C5H4)- (CH2)n-NH2}] (with n=1 or 2)

  摘要：

  The reactions of palladium(II) salts with the primary ferrocenylamines: [(eta(5)-C5H5)Fe{(eta(5)-C5H4)-(CH2)(n)-NH2}] [with n = 1 (1a)(-) or 2 (1b)] are reported. These substrates react with Na-2[PdCl4] in methanol at room temperature giving: [Pd{(eta(5)-C5H5)Fe[(eta(5)-C5H4)(CH2)(n)-NH2]}(2)Cl-2] [with n = 1 (2a) or 2 (2b)] with the ferrocenylamine acting as a monodentate N-donor ligand. However, when compounds 1 are treated with Pd(CH3COO)(2) in toluene, followed by the addition of LiBr and the subsequent treatment of the solids formed with triphenylphosphine, the cyclopalladated complexes: [Pd{(eta(5)-C5H5)Fe[(eta(5)-C5H3)-(CH2)(n)-NH2]}Br(PPh3)] with [n = 1 (3a) or 2 (3b)] were obtained. NMR studies reveal that compounds 3 contain a five- (in 3a) or a six- (in 3b) membered metallacycle fused with the ferrocenyl unit. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00276-9
• 作为产物：
  描述：

  (aminomethyl)ferrocene 、 palladium diacetate 、 三苯基膦 、 lithium bromide 以 甲苯 、 苯 为溶剂， 以38%的产率得到
  参考文献：
  名称：

  Palladium (II) compounds containing mono- and bidentate primary ferrocenylamines. a study of the cyclopalladation of: [ (η5-C5H5)Fe{ (η5-C5H4)- (CH2)n-NH2}] (with n=1 or 2)

  摘要：

  The reactions of palladium(II) salts with the primary ferrocenylamines: [(eta(5)-C5H5)Fe{(eta(5)-C5H4)-(CH2)(n)-NH2}] [with n = 1 (1a)(-) or 2 (1b)] are reported. These substrates react with Na-2[PdCl4] in methanol at room temperature giving: [Pd{(eta(5)-C5H5)Fe[(eta(5)-C5H4)(CH2)(n)-NH2]}(2)Cl-2] [with n = 1 (2a) or 2 (2b)] with the ferrocenylamine acting as a monodentate N-donor ligand. However, when compounds 1 are treated with Pd(CH3COO)(2) in toluene, followed by the addition of LiBr and the subsequent treatment of the solids formed with triphenylphosphine, the cyclopalladated complexes: [Pd{(eta(5)-C5H5)Fe[(eta(5)-C5H3)-(CH2)(n)-NH2]}Br(PPh3)] with [n = 1 (3a) or 2 (3b)] were obtained. NMR studies reveal that compounds 3 contain a five- (in 3a) or a six- (in 3b) membered metallacycle fused with the ferrocenyl unit. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00276-9