vanillin | 1064705-49-2

• 英文名称: vanillin
• 英文别名: (m-carboranyl)OCOC6H3(OCH3)CHO
• CAS: 1064705-49-2
• 化学式: C₁₁H₁₈B₁₀O₄
• 分子量: 322.372
• InChiKey: TXRZYLMBAYNYSR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  vanillin 、 2-萘胺 以 甲醇 为溶剂， 以89%的产率得到(E)-2-methoxy-4-[N-(2-naphthalene)imino]phenyl-m-carboranecarboxylate
  参考文献：
  名称：

  Synthesis of 2-alkoxy-4-[N-(alkyl, cycloalkyl, aryl)imino]phenyl m-carboranecarboxylates

  摘要：

  Previously unknown m-carborane-containing azomethines (Schiff bases) were synthesized by the reaction of esters derived from vanillin or vanillal and m-carboranecarboxylic acid with primary amines in absolute methanol.

  DOI：

  10.1134/s1070363207090162

文献信息

• Synthesis of 2-R-1,3-dioxanes, derivatives of functionally substituted aldehydes of vanillin series
  作者：E. A. Dikusar、V. I. Potkin、T. D. Zvereva、N. A. Zhukovskaya、S. K. Petkevich、A. S. Pavlyuchenkova、M. Yu. Murashova、A. P. Polikarpov、A. A. Shunkevich、A. P. Yuvchenko、R. M. Zolotar’

  DOI：10.1134/s1070428013020085

  日期：2013.2

  By the condensation of substituted aldehydes of vanillin series with 1,3-propanediol in boiling benzene in the presence of sulfo cation exchanger FIBAN K-1 as catalyst functionally 2-R-substituted 1,3-dioxanes were synthesized.
• Synthesis of functionally substituted 2,2′-arylmethylenebis(3-hydroxy-5,5-dimethylcyclohex-2-enones)
  作者：E. A. Dikusar、V. I. Potkin、S. K. Petkevich、R. M. Zolotar’、O. P. Chepik

  DOI：10.1134/s1070363214070068

  日期：2014.7
• Synthesis of 1,3- and 1,4-bis-methoxy- and ethoxy-4-(m-carborane-C-methanoyloxy)phenylmethylene- and phenylmethyl]phenylenediamines
  作者：E. A. Dikusar、V. I. Potkin、N. G. Kozlov、A. P. Kadutskii、A. P. Yuvchenko、M. P. Bey、A. V. Shchurivskaya

  DOI：10.1134/s1070363208110121

  日期：2008.11

  1,3- and 1,4-bis[3-methoxy and ethoxy-4-(m-carborane-C-methanoyloxy)phenylmethylene]phenylenediamines were synthesized from the vanillin and vanillal m-carborane-C-carboxylates by the reaction with 1,3- and 1,4-phenylenediamines in anhydrous methanol. Reduction of the title compounds with Na[BH(OAc)(3)] in benzene yielded 1,3- and 1,4-bis[3-methoxy- and ethoxy-4-(m-carborane-C-methanoyloxy)phenylmethyl] phenylenediamines.