bis[di-n-butyl(2-maleimidoacetato)-tin(IV)]oxide | 666860-12-4

• 英文名称: bis[di-n-butyl(2-maleimidoacetato)-tin(IV)]oxide
• CAS: 666860-12-4；913842-99-6
• 化学式: C₅₆H₈₈N₄O₁₈Sn₄
• 分子量: 1580.17
• InChiKey: NIWVLUUEVYLLDC-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-马来酰亚胺基乙酸 、 二正丁基氧化锡 以 乙醇 、 甲苯 为溶剂， 以93%的产率得到bis[di-n-butyl(2-maleimidoacetato)-tin(IV)]oxide
  参考文献：
  名称：

  Biologically potent organotin(IV) complexes of 2-maleimidoacetic acid

  摘要：

  The in vitro LD50, anti-bacterial, anti-fungal and anti-yeast bio-tests are carried out, which proved them to be powerful biocides. The in vitro anti-tumour and analgesic activities also displayed excellent potential of the title compounds. Series of organotin(IV) complexes are synthesized and characterized. Based on spectroscopic analysis and literature evidences, the compound 1 is tetrahedral and 2 distorted octahedral or trigonal bipyramidal in nature wherein the compounds 3 and 4 are tetrahedral in solid and polymeric trigonal bipyramidal geometry in solution. Beside to H-1, C-13 and Sn-119 NMR, the FT-IR is successfully applied to verify the bonding mode of endo and exo status of tin(IV) of compound 2. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.10.007