[Bu2(2-(2,4-diethylbenzoyl)benzoate))SnOSn(2-(2,4-diethylbenzoyl)benzoate))Bu2]2 | 1176903-01-7

• 英文名称: [Bu2(2-(2,4-diethylbenzoyl)benzoate))SnOSn(2-(2,4-diethylbenzoyl)benzoate))Bu2]2
• CAS: 1176903-01-7
• 化学式: C₁₀₄H₁₄₀O₁₄Sn₄
• 分子量: 2089.09
• InChiKey: VMIDXZWTJTWZRE-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-(2,4-diethylbenzoyl)benzoic acid 、 二正丁基氧化锡 以 苯 为溶剂， 以53.2%的产率得到[Bu2(2-(2,4-diethylbenzoyl)benzoate))SnOSn(2-(2,4-diethylbenzoyl)benzoate))Bu2]2
  参考文献：
  名称：

  Synthesis, crystal structure and biological activities of four novel tetranuclear di-organotin(IV) carboxylates

  摘要：

  Four complexes: [Bu-2(L-1)SnOSn(L-1)Bu-2](2) (1), [Bu-2(L-2)SnOSn(L-2)Bu-2](2) (2), [Bu-2(L-3)SnOSn(L-3)Bu-2](2) (3), and [Bu-2(L-4)SnOSn(L-4)Bu-2](2) (4), (HL1 = 2-(4-methylbenzoyl)benzoic acid, HL2 = 2-(2,4-diethylbenzoyl)benzoic acid, HL3 = 2-(4-chlorobenzoyl)benzoic acid, HL4 = 2-(4-isopropylbenzoyl)benzoic acid) have been prepared and structurally characterized by means of elemental analysis and vibrational, H-1 NMR and FT-IR spectroscopies. The crystal structures of all complexes have been determined by X-ray crystallography. Three distannoxane rings are present to the dimeric tetraorganodistannoxane of planar ladder arrangement. Each structure is centro-symmetric and features a central rhombus Sn2O2 unit with two additional tin atoms linked at the O atoms. Complex 1 exhibited good antibacterial and antitumor activities and have a potential to be used as drugs. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.03.025