{Ru2(CO)4(triisopropylphosphine)2(1,8-diaminonaphthalene(2-))} | 133288-27-4

• 英文名称: {Ru2(CO)4(triisopropylphosphine)2(1,8-diaminonaphthalene(2-))}
• CAS: 133288-27-4
• 化学式: C₃₂H₅₀N₂O₄P₂Ru₂
• 分子量: 790.848
• InChiKey: MCNJFZRXKJKWOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {Ru2(CO)4(triisopropylphosphine)2(1,8-diaminonaphthalene(2-))} 、 mercury(II) thiocyanate 以 四氢呋喃 为溶剂， 以>80的产率得到{Ru2(CO)4(triisopropylphosphine)2(1,8-diaminonaphthalene(2-))}Hg(thiocyanate)2
  参考文献：
  名称：

  Cabeza, Javier A.; Fernández-Colinas, José M.; García-Granda, Santiago, Inorganic Chemistry, 1992, vol. 31, # 7, p. 1233 - 1238

  摘要：

  DOI：
• 作为产物：
  描述：

  1,8-二氨基萘 在 carbon monoxide 作用下， 以 甲苯 为溶剂， 生成 {Ru2(CO)4(triisopropylphosphine)2(1,8-diaminonaphthalene(2-))}
  参考文献：
  名称：

  Cabeza, Iavier A.; Fernandez-Colinas, Iose M.; Riera, Victor, Journal of the Chemical Society, Dalton Transactions

  摘要：

  DOI：

文献信息

• Selective insertion of mercury(<scp>II</scp>) halides into the ruthenium–mercury bonds of trinuclear Ru₂Hg clusters
  作者：Javier A. Cabeza、José M. Fernández-Colinas、Santiago García-Granda、Víctor Riera、Juan F. Van der Maelen

  DOI：10.1039/c39910000168

  日期：——

  The complex [Ru2(µ-dan)(CO)4(PPri3)2]1(H2dan = naphthalene-1,8-diamine) reacts with HgX2(X = Cl, Br or I) to give the trinuclear clusters [(1)HgX2] which react with HgZ2(Z = Cl, Br or I) to form the insertion products [(1)Hg(µ-Z)2HgX2] only when Z is more electronegative than X, otherwise the addition products [(1)Hg(µ-X)2HgZ2] are obtained; the X-ray structure of [(1)Hg(µ-Cl)2HgCl2] has been determined.

  复合物 [Ru2(Âμ-dan)(CO)4(PPri3)2]1(H2dan = -1,8-diamine)与HgX2(X = Cl, Br或I)进行反应,以产生与HgZ2(Z = Cl, Br或I)进行反应的三核集群((1)HgX2)以形成插入产品((1)Hg(Âμ-Z)2HgX2)只有当Z比X更为电子消极时,否则将获得附加产品((1)Hg(Âμ-X)2HgZ2);已确定了((1)Hg(Âμ-Cl)2HgCl2)的X射线结构。
• The addition of protons and metallic electrophiles to the electron-rich RuRu bond of [Ru2(μ,-dan)(CO)4(PiPr3)2]. X-ray structure of [Ru2(μ-AgPPh3)(μ-dan)(CO)4(PiPr3)2][BF4]·CH2Cl2 (dan=1,8-diamidonaphthalene)
  作者：Javier A. Cabeza、José M. Fernández-Colinas、Victor Riera、Santiago García-Granda、Juan F. van der Maelen

  DOI：10.1016/s0020-1693(00)85443-2

  日期：1991.7

  The ruthenium(I) complex [Ru2(mu-dan)(CO)4(P(i)Pr3)2] (1) (dan = 1,8-diamidonaphthalene) reacts with HBF4.OEt2, [AuCl(PPh3)]/TIPF6 and AgBF4/PPh3 to give the cationic complexes [Ru2(mu-M)(mu-dan)(CO)4(P(i)Pr3)2]+ (M = H (2), AuPPh3 (3), AgPPh3 (4)), while the reactions with [AuCl(tht)] (tht = tetrahydrothiophene) and AgO2CCF3 give the neutral derivatives [Ru2(mu-M)(mu-dan)(CO)4(P(i)Pr3)2] (M = AuCl (5), AgO2CCF3 (6)). Complex 1 also reacts with SnCl2 to give [Ru2(mu-SnCl2)(mu-dan)(CO)4(P(i)Pr3)2] (7), but in solution it dissociates SnCl2 unless a large excess of the latter is present. in all cases, the added electrophiles symmetrically bridge the Ru-Ru bond of complex 1, as indicated by IR and NMR spectroscopies. The structure of complex 4 has been confirmed by X-ray diffraction methods.