trans-Fe(CO)2(CS2)(μ-2-(diphenylphosphino)pyridine)2 | 146026-07-5

• 英文名称: trans-Fe(CO)2(CS2)(μ-2-(diphenylphosphino)pyridine)2
• 英文别名: trans-Fe(CO)2(CS2)(Ph2Ppy)2
• CAS: 146026-07-5；191680-57-6
• 化学式: C₃₇H₂₈FeN₂O₂P₂S₂
• 分子量: 714.568
• InChiKey: LDCZQIIFLAZCRD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-Fe(CO)2(CS2)(μ-2-(diphenylphosphino)pyridine)2 、 mercury(II) thiocyanate 以 二氯甲烷 为溶剂， 以67%的产率得到(NCS)Fe(CO)2(μ-2-(diphenylphosphino)pyridine)2Hg(SCN)
  参考文献：
  名称：

  Binuclear complexes containing an iron(I)-mercury(I) bond from oxidation of trans-[Fe(CO)2(CS2)(Ph2Ppy-P)2] with HgX2 (Ph2Ppy = 2-(diphenylphosphino) pyridine, X = Cl, SCN)

  摘要：

  trans-[Fe(CO)(2)(CS2)(Ph(2)Ppy-P)(2)] reacts with HgX2 (X = Cl, SCN) in dichloromethane at room temperature to give heterodinuclear complexes XFe(CO)(2)(mu-Ph(2)Ppy)(2)HgX (X = SCN, 1; X = Cl, 2) containing an iron(I)-mercury(I) bond. The Fe(I)-Hg(O) bond length as determined by X-ray analysis is 2.527(2)Angstrom for 1 and 2.529(1)Angstrom for 2.

  DOI：

  10.1016/s0022-328x(96)06891-x

文献信息

• Reaction of 2-(diphenylphosphino)-pyridine and -thiazole organoiron(0) polydentate ligands with iron(III) salts
  作者：Shan-Ming Kuang、Zheng-Zhi Zhang、Feng Xue、Thomas C.W Mak

  DOI：10.1016/s0277-5387(99)00256-9

  日期：1999.11

  The reaction of trans-Fe(CO)(2)(CS2)(Ph(2)Ppy-P)(2) (Ph(2)Ppy=2-(diphenyhhosphino)pyridine) with FeCl3 resulted in the formation of the binuclear complex [eta(2)-Ph2P(O)py](2)Fe(mu-Cl)(2)FeCl2 (1), while the reaction of trans-Fe(CO)(3) (Ph(2)Ptaz-P)(2) (Ph(2)Ptaz=2-(diphenylphosphino)thiazole) with Fe(NCS)(3) gave Fe(NCS)(2)[eta(2)-Ph2P(O)taz](2) (2). The crystal structures of (1) and (2)C6H6 have been determined using X-ray crystallography. (C) 1999 Elsevier Science Ltd. All rights reserved.