Ionization and Dissociation of Perchlorylfluoride by Electron Impact
作者:Vernon H. Dibeler、Robert M. Reese、D. E. Mann
DOI:10.1063/1.1743661
日期:1957.7
Relative abundances and appearance potentials are reported for both positive and negative ions observed in the mass spectrum of perchlorylfluoride. Appearance potentials of the atom ions result in a value for ΔHf(ClO3F) of nearly zero within the experimental uncertainty. Bond dissociation energies and ionization potentials of the chloryl radicals are estimated from appearance potentials of the polyatomic ions. The energetics of probable ionization-dissociation processes are compared with observed data.