[PtClMe(2,9-dimethyl-1,10-phenanthroline)(CH2=CHOH)] | 198629-52-6

• 英文名称: [PtClMe(2,9-dimethyl-1,10-phenanthroline)(CH2=CHOH)]
• CAS: 198629-52-6
• 化学式: C₁₇H₁₉ClN₂OPt
• 分子量: 497.884
• InChiKey: YYAXWOYFWSCGBM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [PtClMe(2,9-dimethyl-1,10-phenanthroline)(CH2=CHOH)] 、 乙酸酐 以 乙酸酐 为溶剂， 生成 [PtClMe(2,9-dimethyl-1,10-phenanthroline)(CH2=CHOCOMe)]
  参考文献：
  名称：

  Stabilization of unstable unsaturated molecules in five-coordinate TBP complexes of Pt(II): vinyl alcohol derivatives

  摘要：

  Vinyl alcohol has been stabilized in the equatorial position of trigonal bipyramidal Pt(II) complexes [PtX(Y)(dmphen)(CH2=CHOH)] (X=Cl,Br,I; Y=Cl,Me; dmphen=2,9-dimethyl-1,10-phenanthroline). The olefin can be functionalized by reactions with electrophiles, e.g. acetyl chloride and trichloroacetylisocyanate afford the corresponding complexes of vinyl acrylate and vinyl trichloroacetylcarbamate, respectively. Alternatively, addition of KOH to [PtCl(Y)(dmphen)(CH2=CHOH)] species yields the square-planar 2-oxoethyl products [Pt(Y)(CH2CHO)(dmphen)]. The X-ray crystal structure of [PtBrMe(dmphen)(CH2=CHOH)] discloses that the two olefin carbon atoms are symmetrically coordinated to the Pt atom. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05669-7
• 作为产物：
  描述：

  盐酸 、 [PtMe(CH2CHO)(2,9-dimethyl-1,10-phenanthroline)] 以 盐酸 、 氯仿 为溶剂， 生成 [PtClMe(2,9-dimethyl-1,10-phenanthroline)(CH2=CHOH)]
  参考文献：
  名称：

  Stabilization of unstable unsaturated molecules in five-coordinate TBP complexes of Pt(II): vinyl alcohol derivatives

  摘要：

  Vinyl alcohol has been stabilized in the equatorial position of trigonal bipyramidal Pt(II) complexes [PtX(Y)(dmphen)(CH2=CHOH)] (X=Cl,Br,I; Y=Cl,Me; dmphen=2,9-dimethyl-1,10-phenanthroline). The olefin can be functionalized by reactions with electrophiles, e.g. acetyl chloride and trichloroacetylisocyanate afford the corresponding complexes of vinyl acrylate and vinyl trichloroacetylcarbamate, respectively. Alternatively, addition of KOH to [PtCl(Y)(dmphen)(CH2=CHOH)] species yields the square-planar 2-oxoethyl products [Pt(Y)(CH2CHO)(dmphen)]. The X-ray crystal structure of [PtBrMe(dmphen)(CH2=CHOH)] discloses that the two olefin carbon atoms are symmetrically coordinated to the Pt atom. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05669-7