(σ-N,σ-N'-1,4-di(4-methoxyphenyl)-1,4-diaza-1,3-butadiene)(η(2)-(E)-dimethylbut-2-ene-1,4-dioate)platinum(0) | 411208-69-0

• 英文名称: (σ-N,σ-N'-1,4-di(4-methoxyphenyl)-1,4-diaza-1,3-butadiene)(η(2)-(E)-dimethylbut-2-ene-1,4-dioate)platinum(0)
• CAS: 411208-69-0
• 化学式: C₂₂H₂₄N₂O₆Pt
• 分子量: 607.522
• InChiKey: HWFPMHHFGYBZIS-VJAUHHDXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(cycloocta-1,5-diene)platinum(0) 、 1,4-bis(4'-methoxyphenyl)-1,4-diazabuta-1,3-diene 、 1,4-dimethyl but-2-enedioate 以 乙醚 为溶剂， 以15%的产率得到(σ-N,σ-N'-1,4-di(4-methoxyphenyl)-1,4-diaza-1,3-butadiene)(η(2)-(E)-dimethylbut-2-ene-1,4-dioate)platinum(0)
  参考文献：
  名称：

  Synthesis of new (σ2-N,N′-diazadiene)(η2-alkene)platinum(0) compounds

  摘要：

  Novel, thermally stable, dark-red to orange Pt-0(sigma(2)-N,N'-diazadiene)( eta(2) -alkene) compounds have been synthesized in good yields from Pt-0(COD)(2) or Pt-0(NBE)(3), by stepwise substitution of the respective dienes or alkencs by an electron-poor alkene (dimethyl fumarate, maleic anhydride or fumaronitrile), followed by the appropriate diazadiene ligand in dry diethyl ether at 20 degreesC (diazadiene = various N, N'-disubstitued-1,4-diaza-1,3-dienes). The complex Pt(DBA)2 is less suited as a precursor for the synthesis of pt(0)(sigma(2)-N,N'-diazadiene) (eta(2)-alkene) compounds. These zerovalent Pt(diazadiene)(eta(2) -alkene) compounds constitute a useful category of starting materials for synthetic organoplatinum chemistry and catalysis. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00676-4