[Me6In3(OMe)(2,2'-methylenebis(4-methyl-6-tert-butylphenolate)] | 1187925-67-2

• 英文名称: [Me6In3(OMe)(2,2'-methylenebis(4-methyl-6-tert-butylphenolate)]
• CAS: 1187925-67-2
• 化学式: C₃₀H₅₁In₃O₃
• 分子量: 804.193
• InChiKey: HRICLGRQPCUKMM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 2,2'-亚甲基双-(4-甲基-6-叔丁基苯酚) 、 三甲基铟 以 甲醇 、 乙醚 为溶剂， 以90%的产率得到[Me6In3(OMe)(2,2'-methylenebis(4-methyl-6-tert-butylphenolate)]
  参考文献：
  名称：

  Synthesis and Structural Characterization of Some Alkylindium Bisphenoxides

  摘要：

  Alkylindium bisphenoxides stabilized by a methoxy group, Me6In3(OMe)(EDBP)(1) and Me6In3(OMe)(MMBP) (2) (where EDBP-H-2 = 2,2'-ethylidenebis(4,6-di-tert-butyl-phenol) and MMBP-H-2 = 2,2'-methylenebis(4-methyl-6-tert-butylphenol)), hate been synthesized in reaction of bulky bisphenols with Me3In and Me2InO Me in a 1:2:1 molar ratio of the reagents. In contrast, under the same conditions, 2,2'-methylenediphenol forms the complex without a methoxy group, Me5In3(OC6H4CH2C6H4O)(2) (3), as the only product. The molecular structures of 1-3 have been determined by X-ray crystallography.

  DOI：

  10.1021/om900585y