[Cp*CoCp(CH2)11Si(Me2)CH2I][PF6] | 1149367-27-0

• 英文名称: [Cp*CoCp(CH2)11Si(Me2)CH2I][PF6]
• CAS: 1149367-27-0
• 化学式: C₂₉H₄₉CoISi*F₆P
• 分子量: 756.655
• InChiKey: XBTDIOXYZBEMFJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cp*CoCp(CH2)11Si(Me2)CH2I][PF6] 、 对苯二酚 在 K₂CO₃ 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以74%的产率得到[Cp*CoCp(CH2)11Si(Me2)CH2OC6H4OH][PF6]
  参考文献：
  名称：

  Giant Cobalticinium Dendrimers

  摘要：

  Giant redox dendrimers were synthesized with pentamethylcobalticinium termini for the fifth, sixth, and seventh generations (in addition to the nine-arm generation 0) up to a theoretical number of 3(9) tethers (seventh generation, G(7)). Therefore, a functional pentamethyl cobalticinium derivative was synthesized with a long arm. This tether-lengthening strategy was used as in the previously reported ferrocenyl and pentamethylferrocenyl series to overcome the bulk constraint at the periphery of short-tethered dendrimers. These polycationic cobalt-sandwich metallodendrimers were characterized by H-1, C-13, and Si-29 NMR, MALDI-TOF mass spectrometry (for generation 0), elemental analysis, UV-vis spectroscopy, dynamic light scattering (DLS), atomic force microscopy (AFM), and cyclic voltammetry. UV-vis spectroscopy and analytical data are consistent with a moderate amount of defects (G(5) and G(6)) that largely increases for G7 (which contains 14 000 +/- 1000 pentamethylcobalticinium termini). Cyclic voltammetry reveals full chemical and electrochemical reversibility for the cathodic reduction [dendr-(C5H4CoCp)-Cp-III*](+) -> [dendr-(C5H4COCp)-Cp-III*] up to G(7) as in the iron-sandwich series, showing that electron transfer is fast among the flexible peripheral redox sites.

  DOI：

  10.1021/om900079y
• 作为产物：
  描述：

  [Cp*CoCp(CH2)11Si(Me2)CH2Cl][PF6] 、 sodium iodide 以 丁酮 为溶剂， 以91%的产率得到[Cp*CoCp(CH2)11Si(Me2)CH2I][PF6]
  参考文献：
  名称：

  Giant Cobalticinium Dendrimers

  摘要：

  Giant redox dendrimers were synthesized with pentamethylcobalticinium termini for the fifth, sixth, and seventh generations (in addition to the nine-arm generation 0) up to a theoretical number of 3(9) tethers (seventh generation, G(7)). Therefore, a functional pentamethyl cobalticinium derivative was synthesized with a long arm. This tether-lengthening strategy was used as in the previously reported ferrocenyl and pentamethylferrocenyl series to overcome the bulk constraint at the periphery of short-tethered dendrimers. These polycationic cobalt-sandwich metallodendrimers were characterized by H-1, C-13, and Si-29 NMR, MALDI-TOF mass spectrometry (for generation 0), elemental analysis, UV-vis spectroscopy, dynamic light scattering (DLS), atomic force microscopy (AFM), and cyclic voltammetry. UV-vis spectroscopy and analytical data are consistent with a moderate amount of defects (G(5) and G(6)) that largely increases for G7 (which contains 14 000 +/- 1000 pentamethylcobalticinium termini). Cyclic voltammetry reveals full chemical and electrochemical reversibility for the cathodic reduction [dendr-(C5H4CoCp)-Cp-III*](+) -> [dendr-(C5H4COCp)-Cp-III*] up to G(7) as in the iron-sandwich series, showing that electron transfer is fast among the flexible peripheral redox sites.

  DOI：

  10.1021/om900079y