trans-(P,P)-[Ir(CO)(PPh3)(2-(diphenylphosphanyl)anilido-κN,κP)] | 199164-73-3

• 英文名称: trans-(P,P)-[Ir(CO)(PPh3)(2-(diphenylphosphanyl)anilido-κN,κP)]
• 英文别名: [Ir(CO)(P(phenyl)3)(2-(phenyl)2PC6H4NH-κN,κP)]
• CAS: 199164-73-3
• 化学式: C₃₇H₃₀IrNOP₂
• 分子量: 758.819
• InChiKey: UJZJWZYVSSIHLN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  trans-(P,P)-[Ir(CO)(PPh3)(2-(diphenylphosphanyl)anilido-κN,κP)] 、 二氧化硫 以 甲苯 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  Dahlenburg, Lutz; Herbst, Konrad, Chemische Berichte, 1997, vol. 130, # 11, p. 1693 - 1698

  摘要：

  DOI：
• 作为产物：
  描述：

  bis(triphenylphosphine)iridium(I) carbonyl chloride 、 2-(二苯基膦)苯胺 在 n-BuLi 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以87%的产率得到trans-(P,P)-[Ir(CO)(PPh3)(2-(diphenylphosphanyl)anilido-κN,κP)]
  参考文献：
  名称：

  Dahlenburg, Lutz; Herbst, Konrad, Chemische Berichte, 1997, vol. 130, # 11, p. 1693 - 1698

  摘要：

  DOI：

文献信息

• Funktionelle Phosphane
  作者：Lutz Dahlenburg、Konrad Herbst、A Zahl

  DOI：10.1016/s0022-328x(00)00519-2

  日期：2000.12

  significant activity for the reduction of the carbonyl group. Evidence is presented that the catalytic cycle is entered by the formation of the cis-(H,H)-cis-(P,P)-dihydride [IrH2(CO)(PPh3)(2-Ph2PC6H4NH-κN,κP)] (9a) which can be observed by 1H NMR under 45 bar H2. The homogeneous hydrogenation of five α,β-unsaturated carbonyl compounds (crotonaldehyde, ethyl vinyl ketone, 2-cyclohexen-1-one, benzylideneacetone

  饱和和不饱和酮和醛的存在下的催化氢化物[Ir（CO）（PPH 3）（2-PH 2 PC 6 H ^ 4 NR-κ Ñ，κ P）]（R = H：1 ; R =我：2），铑[Rh（CO）（PPH 3）（2-PH 2 PC 6 H ^ 4 NR-κ ñ，κ P）]（R = H：3 ; R =我：4），的[Rh（PPH 3）2（2-PH 2 PC 6 H ^ 4 NH-κ ñ，κ P）]（5）和[Ir（CO）（PPH 3）（2-PH 2 PC 6 H ^ 4 N C（O）camph-（1个小号）} - κ Ñ，κ P）]（6，C（O）樟脑-（1 S）=（1 S）-樟脑酰基）已被研究。出试图复合的，只有1显示显著活性羰基的还原。证据表明，催化循环是通过形成顺-（H，H）-顺-（P，P）-二氢化物[IrH 2（CO）（PPh 3））（2-PH 2 PC 6 H ^ 4 NH-κ Ñ，κ P）]（图9a），它可以通过可观察到1
• Ligand vs. Metal Basicity: Reactions of 2-(Diphenylphosphanyl)anilido and 2-(Diphenylphosphanyl)phenolato Complexes of Rhodium(I) and Iridium(I) with HBF₄
  作者：Lutz Dahlenburg、Konrad Herbst

  DOI：10.1515/znb-2010-0322

  日期：2010.3.1

  Treatment of [M(CO)(PPh3)(2-Ph2PC6H4NR-κN,κP)], where M/NR = Rh/NH (1), Rh/NCH3 (2), Ir/NH (3), and Ir/NCH3 (4), with Et2O・HBF4 in CH2Cl2 resulted in protonation at nitrogen with formation of [M(CO)(PPh3)(2-Ph2PC6H4NHR-κN,κP)]BF4 [M/NHR = Rh/NH2 (7), Rh/NHCH3 (8), Ir/NH2 (9), Ir/NHCH3 (10)]. Similar protonation of [Rh(CO)(PPh3)(2-Ph2PC6H4O-κO,κP)] (5) in CH2Cl2 afforded [Rh(CO)(PPh3)(2-Ph2PC6H4OH-κO

  [M(CO)(PPh3)(2-Ph2PC6H4NR-κN,κP)] 的处理，其中 M/NR = Rh/NH (1)、Rh/NCH3 (2)、Ir/NH (3) 和 Ir/ NCH3 (4)，在 CH2Cl2 中与 Et2O·HBF4 导致在氮质子化，形成 [M(CO)(PPh3)(2-Ph2PC6H4NHR-κN,κP)]BF4 [M/NHR = Rh/NH2 (7)， Rh/NHCH3 (8)、Ir/NH2 (9)、Ir/NHCH3 (10)]。[Rh(CO)(PPh3)(2-Ph2PC6H4O-κO,κP)] (5) 在 中的类似质子化得到 [Rh(CO)(PPh3)(2-Ph2PC6H4OH-κO,κP)]BF4 (11)，但如果在 CH3CN 中进行，则提供 [Rh(CO)(PPh3)- (NCCH3)(2-Ph2PC6H4OH-κP)]BF4 (12)。[Ir(CO
• Rhodium and iridium complexes with 2-(diphenylphosphanyl)anilido ligands: reactions with phenylacetylene and dimethyl acetylenedicarboxylate †
  作者：Lutz Dahlenburg、Konrad Herbst

  DOI：10.1039/a906430c

  日期：——

  Treatment of [Ir(CO)(PPh3)(‘PNMe’)] (‘PNMe’ = 2-Ph2PC6H4NMe–) with phenylacetylene resulted in oxidative addition and opening of the chelate ring to afford mono- and bis-(alkynyl) derivatives, [IrH(CCPh)(CO)(PPh3)(‘PNMe’)] 1 and [IrH(CCPh)2(CO)(PPh3)(η1-‘PN(Me)H’)] 2, respectively. Complex 2 exists as two isomers with trans-located phosphane ligands and cis- or trans-coordinated alkynyl groups. The minimum values of the spin–lattice relaxation times, T1(min), observed for the hydride ligands of the two isomers ruled out the possibility of short IrH· · ·HN contacts in 2. Combination of [Ir(CO)(PPh3)(‘PNMe’)] with dimethyl acetylenedicarboxylate (dmad) gave the irida(III)cyclopropene-like complex [IrC2(CO2Me)2}(CO)(PPh3)(‘PNMe’)] 3 as the expected 1∶1 adduct. In contrast, [Rh(CO)(PPh3)(‘PNMe’)] and dmad interacted by insertion of the activated alkyne into the Rh–N bond, forming the seven-membered metallaheterocycle [RhC(CO2Me)C(CO2Me)N(Me)C6H4PPh2-2}(CO)(PPh3)] 4. [Ir(CO)(PPh3)(‘PNH’)] (‘PNH’ = 2-Ph2PC6H4NH–) and dmad reacted to initially produce a mixture of metallacyclic [IrC2(CO2Me)2}(CO)(PPh3)(‘PNH’)] 5 and unchanged starting materials. Subsequent treatment with methanol resulted in the formation of the iridium(III) complex [IrC(O)OMe}C(CO2Me)CH[C(O)OMe]}(PPh3)(‘PNH’)] 6, which X-ray crystallography showed to contain a chelating vinyl ligand featuring substantial carbenoid character.