[2-(Me2NCH2)C6H4]Me2SnCl | 148603-93-4

• 英文名称: [2-(Me2NCH2)C6H4]Me2SnCl
• 英文别名: [2-(N,N-dimethylaminomethyl)phenyl]dimethyltin(IV) chloride；[2-(Me₂NCH₂)C₆H₄]Me₂SnCl；(2-(Me2NCH2C6H4)dimethyltin(IV) chloride
• CAS: 148603-93-4
• 化学式: C₁₁H₁₈ClNSn
• 分子量: 318.434
• InChiKey: BIQLKTGQQYWTJF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  potassium fluoride 、 [2-(Me2NCH2)C6H4]Me2SnCl 以 甲醇 、 二氯甲烷 、 水 为溶剂， 以89%的产率得到2-[(N,N-dimethylaminomethyl)phenyl]dimethylstannylfluoride
  参考文献：
  名称：

  含有 2-(Me2NCH2)C6H4 基团的超配位有机锡 (IV) 卤化物：{2-(Me2NCH2)C6H4}2SnX2 (X = F, Cl, Br, I) 和 {2-(Me2NCH2)C6H4}R2SnX (R = Me, Ph；X = F、Cl、Br、I) 及其溶液行为和固态、基于氢键的超分子结构

  摘要：

  超配位的二有机锡和三有机锡 (iv) 氯化物 [{2-(Me 2 NCH 2 )C 6 H 4 } 2 SnCl 2 ] (la) 和 [{2-(Me 2 NCH 2 )C 6 H 4 }-R 2 SnCl] [R = Me (2a), Ph (3a)] 通过用 [Li{2-(Me2NCH2)C 6 H 4 }] 处理 SnCl 4 或 R 2 SnCl 2 来制备。有机锡 (iv) 氯化物和适当的卤化钾之间的卤化物交换反应得到 [{2-(Me 2 NCH 2 )-C 6 H 4 } 2 SnX 2 ] [X = F (1b), I (1d)] , [{2-(Me 2 NCH 2 )C 6 H 4 }-Me 2 SnX] [X = F (2b), Br (2c), I (2d)] 和 [{2-(Me 2 NCH 2 ) -C 6 H 4 }Ph 2 SnX] [X = F (3b), I (3d)]。它们的溶液行为通过多核（

  DOI：

  10.1002/ejic.200501018
• 作为产物：
  描述：

  二甲基二氯化锡 、 2-(N,N-dimethylaminomethyl)phenyllithium 以 甲苯 为溶剂， 以69%的产率得到[2-(Me2NCH2)C6H4]Me2SnCl
  参考文献：
  名称：

  含有 2-(Me2NCH2)C6H4 基团的超配位有机锡 (IV) 卤化物：{2-(Me2NCH2)C6H4}2SnX2 (X = F, Cl, Br, I) 和 {2-(Me2NCH2)C6H4}R2SnX (R = Me, Ph；X = F、Cl、Br、I) 及其溶液行为和固态、基于氢键的超分子结构

  摘要：

  超配位的二有机锡和三有机锡 (iv) 氯化物 [{2-(Me 2 NCH 2 )C 6 H 4 } 2 SnCl 2 ] (la) 和 [{2-(Me 2 NCH 2 )C 6 H 4 }-R 2 SnCl] [R = Me (2a), Ph (3a)] 通过用 [Li{2-(Me2NCH2)C 6 H 4 }] 处理 SnCl 4 或 R 2 SnCl 2 来制备。有机锡 (iv) 氯化物和适当的卤化钾之间的卤化物交换反应得到 [{2-(Me 2 NCH 2 )-C 6 H 4 } 2 SnX 2 ] [X = F (1b), I (1d)] , [{2-(Me 2 NCH 2 )C 6 H 4 }-Me 2 SnX] [X = F (2b), Br (2c), I (2d)] 和 [{2-(Me 2 NCH 2 ) -C 6 H 4 }Ph 2 SnX] [X = F (3b), I (3d)]。它们的溶液行为通过多核（

  DOI：

  10.1002/ejic.200501018

文献信息

• Products of hydrolysis of C,N-chelated triorganotin(IV) chlorides and use of products as catalysts in transesterification reactions
  作者：Zdeňka Padělková、Tomáš Weidlich、Lenka Kolářová、Aleš Eisner、Ivana Císařová、Thomas A. Zevaco、Aleš Růžička

  DOI：10.1016/j.jorganchem.2007.09.018

  日期：2007.12

  composition of the products is strongly dependent on the nature of the organic groups bound to the tin atom. Di(n-butyl)tin, dimethyltin as well as the diphenyl derivative exhibits an equilibrium between hydroxide and stannoxane forms (oxide), whereas alkyltin species react spontaneously and reversibly with carbon dioxide present in the air to form carbonate species. On the other hand, diphenyl derivatives

  用过量的氢氧化钠水解含有一个L CN螯合配体的三有机锡（IV）氯化物。产品的组成在很大程度上取决于与锡原子结合的有机基团的性质。二（正丁基）锡，二甲基锡以及二苯衍生物在氢氧化物和锡氧烷形式（氧化物）之间显示出平衡，而烷基锡物质与空气中存在的二氧化碳自发和可逆地反应形成碳酸盐物质。在另一方面，二苯基衍生物显示几乎没有与CO反应2朝向碳酸盐，而二-吨丁基取代的锡衍生物在相同的实验条件下稳定，并保留为氢氧化锡。在二甲基锡衍生物的情况下，在空气中反应过程中观察到甲基迁移并伴随着一个L CN螯合配体的置换。所有研究的化合物的锡中心原子的配位几何形状可以描述为三角双锥体，且一个键合的二甲基氨基基团占据一个配位位点。与酯交换反应相比，这些化合物在酯交换反应中的催化活性通常较低，但环己醇对乙酸乙酯的酯交换反应表现出显着的活性。
• Monomeric Triorganotin(IV) Fluorides Containing a C,N-Chelating Ligand
  作者：Josef Bareš、Petr Novák、Milan Nádvorník、Roman Jambor、Tomáš Lébl、Ivana Císařová、Aleš Růžička、Jaroslav Holeček

  DOI：10.1021/om049912q

  日期：2004.6.1

  The set of four triorganotin(IV) fluorides of general formula 2-[(CH3)(2)NCH2]C6H4}R2SnF, where R is Me (5), n-Bu (6), t-Bu (7), and Ph (8), respectively, has been prepared and characterized using NMR and ESI-MS techniques. The structures of crystalline compounds 5 and 8 were determined using X-ray methods. All compounds are monomeric both in solution using different solvents and in the solid state. The tin central atom is five-coordinated with all carbon atoms in equatorial positions and fluorine and nitrogen, from the intramolecularly coordinated dimethylamino group, in the axial positions of the distorted trigonal bipyramid. The ability of compounds 6 and 8 to perform fluorination of organometallic chlorides was tested on titanocene dichloride. A quantitative yield Of CP2TiF2 was obtained.
• Organotin(IV) hypervalent pseudohalides. Synthesis and structural characterization
  作者：Cristina Coza、Adina Stegarescu、Răzvan Şuteu、Anca Silvestru

  DOI：10.1016/j.jorganchem.2014.11.026

  日期：2015.2

  Tri- and diorganotin(IV) pseudohalides of type [2-(Me2NCH2)C6H4]R2Sn(NCE) [E = S, R = Me (1); E = Se, R = Me (2), Ph (3)] and respectively [2-(Me2NCH2)C6H4]RSn(NCE)(2) [E = S, R = Bu-n (4), Ph (5), 2-(Me2NCH2) C6H4 (6); E Se; R 2-(Me2NCH2) C6H4 (7)] were obtained by reacting the appropriateorganotin(IV) chlorides and alkali metal pseudohalides in stoichiometric amounts. The new species were characterized by multinuclear NMR (H-1, C-13, Sn-119 and Se-77 where appropriate), IR spectroscopy and mass spectrometry. Both the Sn-119 NMR and the X-ray diffraction studies evidenced the formation of Sn-NCE bonds in these compounds. For compounds 1-4, 6 and 7 the single-crystal X-ray diffraction studies revealed intramolecular Me2N -> Sn interactions and the formation of hypervalent species 10-Sn-5 in compounds 1-3 and 12-Sn-6 in 4, 6 and 7, respectively. Compounds 1-3 are monomeric species, with monodentate isochalcogenocyanato ligands, while in 4 one of the NCE- ligands behave as a bridging moiety, thus resulting in dimeric associations. Short pi CH gamma-CH2 center dot center dot center dot C-g and respectively C-g center dot center dot center dot C-g intermolecular contacts resulted in polymeric chains of dimmers in 4 and 3D supramolecular networks in 6 and 7, respectively. The reactions of [2-(Me2NCH2)C6H4]RSnCl2 and MECN in an 1:1 molar ratio resulted in the formation of a mixture of [2-(Me2NCH2)C6H4]RSnCl2, [2-(Me2NCH2)C6H4]RSn(NCE)(2) and [2-(Me2NCH2)C6H4]RSnCl(NCE) [E = S, R = Ph (8), 2-(Me2NCH2)C6H4 (9); E = Se, R = 2-(Me2NCH2)C6H4 (10)]. (C) 2014 Elsevier B.V. All rights reserved.