N,N-二氟羟胺 | 57521-42-3

• 中文名称: N,N-二氟羟胺
• 英文名称: N,N-difluorohydroxylamine
• CAS: 57521-42-3
• 化学式: F₂NO
• 分子量: 68.0029
• InChiKey: NTXQKTLDOYDABL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  4.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  23.14
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  氧化亚氮 、 六氟化硫 以 neat (no solvent) 为溶剂， 生成 N,N-二氟羟胺
  参考文献：
  名称：

  Isotope shifts in EPR spectra

  摘要：

  Small changes observed in the 19F isotropic hyperfine interaction in F2NO upon isotopic substitution of the N or O atom are shown to be statistically significant. The effect is attributed to a modulation of the hyperfine interaction by the ν2 bending mode of the free radical.

  DOI：

  10.1063/1.442159

文献信息

• Endothermic Formation of a Chemical Bond by Entropic Stabilization:  Difluoronitroxide Radical in Solid Argon
  作者：Eugenii Ya. Misochko、Alexander V. Akimov、Ilya U. Goldschleger、Alexander I. Boldyrev、Charles A. Wight

  DOI：10.1021/ja982222r

  日期：1999.1.1

  Difluoronitroxide radical (F2NO) has been formed in solid argon matrices by successive addition of two diffusing F atoms to NO. This radical exists in dynamic equilibrium with a van der Waals complex (F-FNO). Measurements of the equilibrium concentrations as a function of temperature show that the changes in enthalpy and the entropy associated with formation of the F2NO radical are Delta H = 1240 +/- 180 J/mol and Delta S = 62 +/- 10 J/(mol K). Because both these quantities are positive, the equilibrium favors F2NO only at elevated temperatures. This situation is a rare case in which formation of a chemical bond is stabilized only by an increase in the entropy of the system.