[(η5-C5H3)2(SiMe2)2]Ru2(CO)4(Br)2 | 405158-48-7

• 英文名称: [(η5-C5H3)2(SiMe2)2]Ru2(CO)4(Br)2
• CAS: 405158-48-7
• 化学式: C₁₈H₁₈Br₂O₄Ru₂Si₂
• 分子量: 716.458
• InChiKey: WPUFVJHQRBPFSG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(η5-C5H3)2(Si(CH3)2)2]Ru2(CO)4 、 溴 以 二氯甲烷 为溶剂， 以85%的产率得到[(η5-C5H3)2(SiMe2)2]Ru2(CO)4(Br)2
  参考文献：
  名称：

  Reactions of the Dinuclear Ruthenium Complex {(η⁵-C₅H₃)₂(SiMe₂)₂}Ru₂(CO)₄, Featuring a Doubly Linked Dicyclopentadienyl Ligand

  摘要：

  The complex {(eta(5-)C(5)H(3))(2)(SiMe2)(2)}Ru-2(CO)(4) (1), which features the doubly linked dicyclopentadienyl ligand (eta(5)-C5H3)(2)(SiMe2)(2), reacts with phosphines (PMe3, PCy3, PPh3) to give {(eta(5)-C5H3)(2)(SiMe2)(2)}Ru-2(CO)(mu-CO)(2)(PR3) (2a-c), with halogens X-2 (X = Cl, Br, I) to give the Ru-Ru-cleaved products {(eta(5)-C5H3)(2)(SiMe2)(2)}Ru-2(CO)(4)(X)(2) (3a-c), with X-2 and AgTfO to give [{(eta(5)-C5H3)(2)(SiMe2)(2)}Ru-2(CO)(4)(mu-X)]+TfO- (X = Cl, Br, I; 4a-c), and with SnCl2 to give {(eta(5)-C5H3)(2)(SiMe2)(2)}Ru-2(CO)(4)(mu-SnCl2) (5), resulting from the insertion of SnCl2 into the Ru-Ru bond. Reduction of 1 with Na/Hg generates {(eta(5)-C5H3)(2)(SiMe2)(2)}Ru-2(CO)(4)](2-) (6), which reacts with (eta(5)-C5H5)(2)TiCl2 to give {(eta(5)-C5H3)(2)(SiMe2)(2)}Ru-2(CO)(4){mu-Ti(eta(5)-C5H5)(2)} (7). Ultraviolet photolysis of 1 with diphenylacetylene and phenylacetylene yields a series of five dinuclear Ru. complexes (8-10, 12, 13) containing one or two bridging acetylene units. The rigidity of the doubly linked (eta(5)-C5H3)(2)(SiMe2)(2) ligand substantially influences the reactivity and structures of the complexes. Molecular structures of 1, 2a, 3c, 5, 9, 10, and 12 as determined by X-ray diffraction studies are also presented.

  DOI：

  10.1021/om010674y