| 632354-19-9

• CAS: 632354-19-9
• 化学式: C₂₀H₂₁ClO₂Zr
• 分子量: 420.063
• InChiKey: IYNLZFGCCNHTRY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 氧气 以 not given 为溶剂， 生成 (μ-oxo)bis[chlorobis(cyclopentadienyl)zirconium(IV)]
  参考文献：
  名称：

  Synthesis of Aryloxo Cyclopentadienyl Group 4 Metal-Containing Dendrimers

  摘要：

  A quantitative procedure for the hydrosilylation of allylic -SiMe3 protected phenols with Et3SiH and Si-H terminated carbosilane dendrimers of first, second, and fourth generations have been performed to give nG-[(CH2)(3){C6H4-r(OMe)(r)}OH](m). The subsequent treatment with [Ti(C5Me5)Cl2Me], [Ti(C5Me5)Me-3], or [Ti(C5H5)(2)ClX] (M = Ti, X = Cl; M = Zr, X = H) afforded the corresponding organometallic metallodendrimers.

  DOI：

  10.1021/om034042i
• 作为产物：
  描述：

  Schwartz's reagent 、 丁香酚 以 四氢呋喃 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Synthesis of Aryloxo Cyclopentadienyl Group 4 Metal-Containing Dendrimers

  摘要：

  A quantitative procedure for the hydrosilylation of allylic -SiMe3 protected phenols with Et3SiH and Si-H terminated carbosilane dendrimers of first, second, and fourth generations have been performed to give nG-[(CH2)(3){C6H4-r(OMe)(r)}OH](m). The subsequent treatment with [Ti(C5Me5)Cl2Me], [Ti(C5Me5)Me-3], or [Ti(C5H5)(2)ClX] (M = Ti, X = Cl; M = Zr, X = H) afforded the corresponding organometallic metallodendrimers.

  DOI：

  10.1021/om034042i