Re(CO)3(bipy)(OSeO2H) | 1120349-65-6

• 英文名称: Re(CO)3(bipy)(OSeO2H)
• CAS: 1120349-65-6
• 化学式: C₁₃H₉N₂O₆ReSe
• 分子量: 554.391
• InChiKey: FZEZNZWJOPAKBW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  rhenium-(2,2'-bipyridine)-triscarbonyl-methyl 、 硒脲酸 以 水 、 乙腈 为溶剂， 生成 Re(CO)3(bipy)(OSeO2H)
  参考文献：
  名称：

  Oxy-Functionalization of Nucleophilic Rhenium(I) Metal Carbon Bonds Catalyzed by Selenium(IV)

  摘要：

  We report that SeO2 catalyzes the facile oxy-functionalization of (CO)(5)Re(I)-Me delta- with IO4- to generate methanol. Mechanistic studies and DFT calculations reveal that catalysis involves methyl group transfer from Re to the electrophilic Se center followed by oxidation and subsequent reductive functionalization of the resulting CH3Se(VI) species. Furthermore, (CO)(3)Re(I)(Bpy)-R (R = ethyl, n-propyl, and aryl) complexes show analogous transfer to SeO2 to generate the primary alcohols. This represents a new strategy for the oxy-functionalization of M-R delta- polarized bonds.

  DOI：

  10.1021/ja806814c