| 63866-73-9

• CAS: 63866-73-9
• 化学式: C₁₃H₉FeNO₄
• 分子量: 299.066
• InChiKey: WFDKUKPZLHSNGP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 cobalt(Cl)2(2,6-xylyl isocyanide)4 在 C₆H₅CH₂NC 作用下， 以 苯 为溶剂， 以100%的产率得到
  参考文献：
  名称：

  Albers, Michel O.; Coville, Neil J.; Singleton, Eric, Journal of the Chemical Society, Dalton Transactions, 1982, p. 1069 - 1080

  摘要：

  DOI：
• 作为产物：
  描述：

  五羰基铁 、 2,6-二甲基苯基异腈 以 苯 为溶剂， 以95%的产率得到
  参考文献：
  名称：

  过渡金属配合物催化的羰基金属取代反应

  摘要：

  的Fe（CO）的反应5与异腈RNC在氯化钴的存在下2 ·2H 2 O作为催化剂，得到的Fe（CO）5- Ñ（RNC）ñ（ñ = 1-5）被报告。

  DOI：

  10.1039/c39800000489

文献信息

• Supported transition metals and metal oxides as catalysts for the metal carbonyl substitution reaction
  作者：Michel O. Albers、Neil J. Coville、Eric Singleton

  DOI：10.1016/0022-328x(87)87126-7

  日期：1987.4

  supported transition metals and metal oxides have been investigated as catalysts for the metal carbonyl substitution reaction M−CO+L → M−L + CO (L = isocyanide (RNC), Group V donor ligand). The use of model substitution reactions reveals the metals Pd, Pt, Ru and Rh and the oxides PdO and PtO2 to be efficient catalysts for substitution reactions of mono-, di- and polynuclear metal carbonyl complexes, and

  已经研究了一系列负载型过渡金属和金属氧化物作为金属羰基取代反应M-CO + L→M-L + CO（L =异氰酸酯（RNC），V组供体配体）的催化剂。模型取代反应的使用揭示了金属Pd，Pt，Ru和Rh和氧化物PdO和PtO 2是单核，二核和多核金属羰基配合物取代反应的有效催化剂，并且有可观察到的影响与催化剂载体的性质，催化剂分散性，催化剂活化和催化剂中毒有关，通常观察到的活性顺序为Pd> Pt> Ru> Rh和PdO> PtO 2。自由基捕集剂对苯二酚和Galvinoxyl对催化具有抑制作用，而光则具有轻微的促进作用。这些观察结果与类似于针对观察到的催化机制[η一致5 Ç 5 ħ 5）的Fe（CO）2 } 2 ]，即自由基非链过程。金属和金属氧化物对于包括[Fe（CO）5- n（CNR）n ]（n = 1-5），[M（CO）6 6- n（CNR）n ]（M = Cr，Mo，W；n = 1-3），[M
• Di- and poly-nuclear transition metal complexes as catalysts for the metal carbonyl substitution reaction. The role of supported metals and metal oxides as catalyst promoters
  作者：Michel O. Albers、Neil J. Coville、Eric Singleton

  DOI：10.1016/0022-328x(87)80159-6

  日期：1987.6

  Various di- and poly-nuclear transition metal complexes have been investigated as catalysts for the metal carbonyl substitution reaction. The complexes [(η5-C5H4R)Fe(CO)2} 2] (R = H, Me, CO2Me, OMe, O(CH2)4OH) and [(η5-C5H5)-Ru(CO)2} 2] are active catalysts for a range of substitution reactions including the probe reaction [Fe(CO)4(CNBut)] + ButNC → [Fe(CO)3(CNBut)2] + CO. [(η5-C5Me5)Fe(CO)2}2]

  已经研究了各种二核和多核过渡金属络合物作为金属羰基取代反应的催化剂。配合物[（η 5 -C 5 H ^ 4 R）的Fe（CO）2 } 2 ]（R = H，Me，CO 2 Me中的OME，O（CH 2）4 OH）和[（η 5 - C 5 H 5）-Ru（CO）2 } 2 ]是用于一系列取代反应的活性催化剂，包括探针反应[Fe（CO）4（CNBu t）] + Bu t NC→[Fe（CO）3（ CNBu t）2 ] + CO。[（η 5 -C 5我5）的Fe（CO）2 } 2 ]是催化活性仅在可见光的照射。对于[η 5 -C 5 H ^ 5）的Fe（CO）2 } 2 ]和一系列ofisocyanides RNC（R =卜吨，C 6 H ^ 5 CH 2，2,6--ME 2 ç 6 ħ 3），催化剂通过与异氰化物取代修饰是影响观察到的催化效应的程度，例如，[（η的一个主要因素5 -C 5
• The catalytic substitution of metal carbonyls and substituted metal carbonyls by isonitriles in the presence of rhodium(I) and polymer-supported rhodium(I) complexes
  作者：Michel O. Albers、Neil J. Coville、Christakis P. Nicolaides、Ronald A. Webber、Terence V. Ashworth、Eric Singleton

  DOI：10.1016/s0022-328x(00)85787-3

  日期：1981.9

  Metal carbonyls and substituted metal carbonyls, under relatively mild reaction conditions, in the presence of isonitriles, undergo catalytic CO substitution by rhodium(I) and polymer-supported rhodium(I) complexes. The reaction provides a facile route to the synthesis of transition metal isonitrile metal isonitrile complexes.

  在相对温和的反应条件下，在异腈存在下，羰基金属和取代的羰基金属通过铑（I）和聚合物负载的铑（I）配合物进行催化CO取代。该反应提供了合成过渡金属异腈金属异腈配合物的简便途径。
• The preparation and spectra of [Fe2(η-C5H5)2(CO)4−n(CNAr)n] complexes. The reaction of [Fe(CO)5−m(CNAr)m] with dicyclopentadiene
  作者：A.R. Manning、Gerard McNally、Paul Soye

  DOI：10.1016/s0020-1693(00)83073-x

  日期：1991.2

  The relatively elusive [Fe2(eta-C5H5)2(CO)4-n(CNAr)n] complexes where n = 1 or 2 and Ar = C6H5, 2-MeC6H4, 4-MeC6H4, 2,4-Me2C6H3, 2,6-Me2C6H3 and 2,4,6-Me3C6H2 have been prepared by two effective, but not completely general routes. One is the light-catalyzed substitution of [Fe2(eta-C5H5)2(CO)4] by ArNC which gives the derivatives where n = 1 or 2 and, eventually, 4. The other is the reaction at 145-degrees-C of dicyclopentadiene with [Fe(CO)5] and ArNC or with [Fe(CO)4(CNAr)], but not with [Fe(CO)3(CNAr)2] or [Fe(CO)4(CNMe)]. The pathway of the reaction of dicyclopentadiene with [Fe(CO)5]or[Fe(CO)4(CNAr)] is discussed and it is concluded that it does not proceed via cyclopentadine and mononuclear cyclopentadienyl complexes but via species containing dicyclopentadiene and two metal atoms which are formed at an early stage in the reaction and which remain associated throughout the reaction up to the formation of the [Fe2(eta-C5H5)2(CO)4-n(CNAr)n] derivatives. The infrared and H-1 NMR spectra of the complexes are reported and discussed.
• Coville, Neil J.; Albers, Michel O.; Singleton, Eric, Journal of the Chemical Society, Dalton Transactions, 1983, p. 947 - 954
  作者：Coville, Neil J.、Albers, Michel O.、Singleton, Eric

  DOI：——

  日期：——