[Re(1,10-phenanthroline)(CO)₃(CH₃CN)](CF₃SO₃) | 161772-64-1

• 英文名称: [Re(1,10-phenanthroline)(CO)₃(CH₃CN)](CF₃SO₃)
• 英文别名: [Re(phen)(CO)₃(CH₃CN)](CF₃SO₃)；[Re(CO)₃(phen)(MeCN)](CF₃SO₃)
• CAS: 161772-64-1
• 化学式: CF₃O₃S*C₁₇H₁₁N₃O₃Re
• 分子量: 640.57
• InChiKey: QBNVMRQQRTVGKC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Re(1,10-phenanthroline)(CO)₃(CH₃CN)](CF₃SO₃) 在 吡啶 作用下， 以 乙腈 为溶剂， 以>90的产率得到[Re(CO)_{3(1,10-phenanthroline)(pyridine)]}⁺
  参考文献：
  名称：

  New mechanism for photosubstitution of organometallic complexes. Generation of substitutionally labile oxidation states by excited-state electron transfer in the presence of ligands

  摘要：

  DOI：

  10.1021/ja00407a050
• 作为产物：
  描述：

  1,10-菲罗啉 以 正庚烷 、 乙腈 为溶剂， 生成 [Re(1,10-phenanthroline)(CO)₃(CH₃CN)](CF₃SO₃)
  参考文献：
  名称：

  rh（I）联吡啶和三联吡啶三羰基配合物催化的烯烃的催化和不对称环丙烷化反应。

  摘要：

  Re（I）三羰基联吡啶和三联吡啶配合物催化烯烃的立体有规环丙烷化；[Re（L）（CO）（3）（MeCN）] OTf配合物（L =手性）可实现较高的环丙烷相对于偶联的选择性以及对苯乙烯的顺式和反式环丙烷的ee分别为73％和62％ C（2）-对称的吡啶吡啶配体）。

  DOI：

  10.1039/b712995e

文献信息

• Synthesis, photophysical, photochemical and electrochemical properties of rhenium(I) diimine complexes with photoisomerizable pyridyl-azo, -ethenyl or -ethyl ligands
  作者：Vivian Wing-Wah Yam、Victor Chor-Yue Lau、Li-Xin Wu

  DOI：10.1039/a801575i

  日期：——

  A series of rhenium(I) diimine complexes with pyridyl-azo, -ethenyl or -ethyl type ligands, [Re(CO)3(N–N)L]ClO4 and [Re(CO)3(N–N)}2L′][ClO4]2 N–N = 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen); L = 4-phenylazopyridine (PHAZO), 4-styrylpyridine (STYPY), [2-(4-pyridyl)ethyl]benzene (PEB), 4-(4-nitrostyryl)pyridine (NSP); L′ = 4,4′-azopyridine (AZO), 1,4-bis[2-(4-pyridyl)ethenyl]benzene (BPENB), 1,4-bis[2-(4-pyridyl)ethyl]benzene (BPEB)} have been synthesized and their photophysical properties studied. The quantum yields for the photoinduced isomerization of the complexes [Re(CO)3(bpy)(NSP)]+ and [Re(CO)3(phen)(NSP)]+ have been determined.

  一系列铼(I)二亚胺配合物，具有吡啶基-偶氮、-乙烯基或-乙基类型的配体，[Re(CO)3(N–N)L]ClO4 和 [Re(CO)3(N–N)}2L′][ClO4]2 N–N = 2,2′-联吡啶 (bpy)、1,10-菲咯啉 (phen); L = 4-苯基偶氮吡啶 (PHAZO)、4-苯乙烯基吡啶 (STYPY)、[2-(4-吡啶基)乙基]苯 (PEB)、4-(4-硝基苯乙烯)吡啶 (NSP); L′ = 4,4′-偶氮吡啶 (AZO)、1,4-双[2-(4-吡啶基)乙烯基]苯 (BPENB)、1,4-双[2-(4-吡啶基)乙基]苯 (BPEB)} 已被合成，并研究了它们的光物理性质。已确定配合物 [Re(CO)3(bpy)(NSP)]+ 和 [Re(CO)3(phen)(NSP)]+ 的光诱导异构化的量子产率。
• Rhenium(I) Polypyridine Diamine Complexes as Intracellular Phosphorogenic Sensors: Synthesis, Characterization, Emissive Behavior, Biological Properties, and Nitric Oxide Sensing
  作者：Alex Wing-Tat Choi、Vicki Man-Wai Yim、Hua-Wei Liu、Kenneth Kam-Wing Lo

  DOI：10.1002/chem.201402502

  日期：2014.7.28

  development of a series of rhenium(I) polypyridine complexes appended with an electron‐rich diaminoaromatic moiety as phosphorogenic sensors for nitric oxide (NO). The diamine complexes [Re(N^N)(CO)3(py‐DA)][PF6] (py‐DA=3‐(N‐(2‐amino‐5‐methoxyphenyl)aminomethyl)pyridine; N^N=1,10‐phenanthroline (phen) (1 a), 3,4,7,8‐tetramethyl‐1,10‐phenanthroline (Me4‐phen) (2 a), 4,7‐diphenyl‐1,10‐phenanthroline (Ph2‐phen)

  我们报告了一系列of（I）聚吡啶配合物的发展，该配合物附有一个富电子的二氨基芳族部分，作为一氧化氮（NO）的生磷传感器。二胺络合物[Re（N ^ N）（CO）3（py-DA）] [PF 6 ]（py-DA = 3-（N-（2-氨基-5-甲氧基苯基）氨基甲基）吡啶; N ^ N = 1,10-菲咯啉（phen）（1 a），3,4,7,8-四甲基-1,10-菲咯啉（Me 4 -phen）（2 a），4,7-二苯基-1,10-菲咯啉（Ph 2- phen）（3 a））已合成并表征。与常见的en（I）二亚胺相反，由于三重态金属到配体的电荷转移（3 MLCT）通过光诱导电子转移（PET）由二氨基芳香族化合物发射。经NO处理后，复合物转化为三唑衍生物[Re（N ^ N）（CO）3（py-triazole）] [PF 6 ]（py-triazole = 3-（（6-6-甲氧基苯并三唑-1-基）甲基）吡啶;
• Rhenium(i) polypyridine complexes functionalized with a diaminoaromatic moiety as phosphorescent sensors for nitric oxide
  作者：Alex Wing-Tat Choi、Che-Shan Poon、Hua-Wei Liu、Heung-Kiu Cheng、Kenneth Kam-Wing Lo

  DOI：10.1039/c3nj00033h

  日期：——

  A series of rhenium(I) polypyridine complexes functionalized with a diaminoaromatic moiety has been developed as phosphorescent sensors for nitric oxide (NO). The diamine complexes [Re(N⁁N)(CO)3(py-diamine)](CF3SO3) [py-diamine = 3,4-diaminopyridine; N⁁N = 1,10-phenanthroline (phen) (1a), 2,9-dimethyl-1,10-phenanthroline (Me2-phen) (2a), 3,4,7,8-tetramethyl-1,10-phenanthroline (Me4-phen) (3a), 4,7-diphenyl-1,10-phenanthroline (Ph2-phen) (4a)] were synthesized and characterized. These complexes were only weakly emissive due to the diaminoaromatic moiety that quenches the 3MLCT [dπ(Re) → π*(N⁁N)] emission by photoinduced electron transfer (PET). However, in the presence of NO, these diamine complexes were converted to the triazole derivatives [Re(N⁁N)(CO)3(py-triazole)](CF3SO3) [py-triazole = 1H-1,2,3-triazolo[4,5,c]pyridine; N⁁N = phen (1b), Me2-phen (2b), Me4-phen (3b), Ph2-phen (4b)], which revealed intense emission upon excitation. The emission of the complexes was independent to pH under neutral and basic conditions (pH > 6). The cytotoxicity and cellular uptake properties of these complexes were studied by the 3-(4,5-dimethyl-2-thiazolyl)-2,5-diphenyltetrazolium bromide (MTT) assay and ICP-MS, respectively. The potential application of these complexes as intracellular NO sensors was also investigated.

  一系列功能化有二氨基芳香基团的铼(I)多吡啶复合物被开发作为一氧化氮（NO）的磷光传感器。这些二胺复合物 [Re(N⁁N)(CO)3(py-diamine)](CF3SO3) [py-diamine = 3,4-二氨基吡啶；N⁁N = 1,10-菲啉（phen）(1a)，2,9-二甲基-1,10-菲啉（Me2-phen）(2a)，3,4,7,8-四甲基-1,10-菲啉（Me4-phen）(3a)，4,7-二苯基-1,10-菲啉（Ph2-phen）(4a)] 被合成并表征。由于二氨基芳香基团通过光致电子转移（PET）使3MLCT [dπ(Re) → π*(N⁁N)]发射被猝灭，这些复合物仅表现出微弱的发射。然而，在NO的存在下，这些二胺复合物转化为三唑衍生物 [Re(N⁁N)(CO)3(py-triazole)](CF3SO3) [py-triazole = 1H-1,2,3-三唑[4,5,c]吡啶；N⁁N = phen (1b)，Me2-phen (2b)，Me4-phen (3b)，Ph2-phen (4b)]，这些衍生物在激发时显示出强烈的发射。在中性和碱性条件下（pH > 6），这些复合物的发射与pH无关。通过3-(4,5-二甲基-2-噻唑基)-2,5-二苯基四唑（MTT）法和ICP-MS分别研究了这些复合物的细胞毒性和细胞摄取特性。此外，还研究了这些复合物作为细胞内NO传感器的潜在应用。
• Molecular rods based on a ruthenium(ii) macrocyclic bis(acetylide) building block
  作者：Mei-Yuk Choi、Michael C. W. Chan、Kung-Kai Cheung、Chi-Ming Che、Shie-Ming Peng

  DOI：10.1039/b002674n

  日期：——

  The prototype of an organometallic linear-rod building block incorporating the saturated σ-donating 16-TMC macrocycle, peripheral pyridine moieties for versatile ligation, and the π-conjugated trans-[Ru(CCpy-4)2] fragment along the molecular axis, is described and applied to the assembly of trimetallic arrays.

  介绍了一种有机金属线性杆构件的原型，该构件包含饱和的σ供体 16-TMC 大环、用于多功能连接的外围吡啶分子以及沿分子轴的π共轭反式-[Ru(CCpy-4)2] 片段，并将其应用于三金属阵列的组装。
• Luminescent Re(I) Carbonyl Complexes as Trackable PhotoCORMs for CO delivery to Cellular Targets
  作者：Indranil Chakraborty、Jorge Jimenez、W. M. C. Sameera、Masako Kato、Pradip K. Mascharak

  DOI：10.1021/acs.inorgchem.6b02999

  日期：2017.3.6

  characteristics of these complexes. The luminescent rheinum(I) photoCORMs uniformly displayed efficient cellular internalization by the human breast adenocarcinoma cells, MDA-MB-231, while the complex with PPh3 as ancillary ligand showed moderate nuclear localization in addition to the cytosolic distribution. These species hold significant promise as theranostic photoCORMs (photoinduced CO releasing molecules)

  通式为[ReX（CO）3（phen）] 0/1 +的Re（I）羰基配合物家族（其中X = Cl –，CF 3 SO 3 –，MeCN，PPh 3衍生自1,10-菲咯啉（phen）的；和甲基咪唑）具有可变的发射特性，具体取决于第六个辅助配体/基团（X）的存在。除X = MeCN外，所有配合物在低功率紫外光照射下均表现出适度的CO释放，并且在厌氧/好氧环境中在溶液中以及在黑暗条件下保持固态时都具有无限的稳定性。这些CO供体根据光照依赖于第六配体的性质释放出三个，一个或不释放一氧化碳，如借助依赖于时间的红外光谱研究的那样。激发态密度泛函理论（DFT）和随时间变化的DFT计算结果为深入了解这些配合物的发射特征提供了依据。3作为辅助配体显示了除胞质分布外的中等核定位。这些物种有望成为治疗上的photoCORM（光诱导释放CO的分子），可以在细胞基质中追踪前药的进入。