C32H26Cr2Mo2O14P2, white | 181496-19-5

• 英文名称: C32H26Cr2Mo2O14P2, white
• 英文别名: ((μ,η(2)-P2(Cr(CO)5)2)(Mo(CO)2(C5H4tBu)2))
• CAS: 181496-19-5
• 化学式: C₃₂H₂₆Cr₂Mo₂O₁₄P₂
• 分子量: 992.37
• InChiKey: QDOWBYDCMKSGGM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  、 以 四氢呋喃 为溶剂， 以27%的产率得到C32H26Cr2Mo2O14P2, white
  参考文献：
  名称：

  Groeer, Thomas; Scheer, Manfred, Zeitschrift fur Anorganische und Allgemeine Chemie, 2000, vol. 626, # 5, p. 1211 - 1216

  摘要：

  DOI：

文献信息

• The reaction of P4 with [Cp′Mo(CO)3]2 (Cp′ = η5-C5H4tBu)—the structure of [Cp′Mo(CO)2<(η3-P4){Cr(CO)5}4(H)>]
  作者：Manfred Scheer、Uta Becker、Jörg Magull

  DOI：10.1016/s0277-5387(97)00480-4

  日期：1998.5

  The photochemical reaction of [Cp'Mo(CO)(3)](2) (Cp' = eta(5)-C(5)H(4)tBu) with white phosphorus in the presence of [Cr(CO)(5)thf] leads to the P-n ligand complexes [Cr(CO)(4)[(eta(4)-P-4)Cr(CO)(5)}(4)]] (1), [Cp'Mo(CO)(2)[(eta(3)-P-4)Cr(CO)(5))(4)(H)]] (2) and [Cp'Mo(CO)(2)}(2)[(mu, eta(2)-P-2)Cr(CO)(5)}(2)]] (3) The products were characterized by NMR, IR and partially by X-ray structure analysis. The reaction proceeds via a P-P bond cleavage leading to the bent cyclo-P-4 complex [Cp'Mo(CO)(2)[(eta(3)-P-4)Cr(CO)(5)}(4)(Cp'Mo(CO)(3)}]] (2a), which hydrolysis during the chromatographic work-up to give the more stable-compound 2. Furthermore, a P-3/P-1 fragmentation of 2a occurs to form the phosphido complex intermediate [Cp'(CO)(2)Mo=P-->Cr(CO)(5)]. The latter dimerises resulting in the formation of the tetrahedral compound 3, containing a Mo2P2 moiety. (C) 1998 Elsevier Science Ltd. All rights reserved.
• Different Ways of P4 Transformation in the Coordination Sphere of Transition Metals
  作者：Manfred Scheer、Kay Schuster、Uta Becker

  DOI：10.1080/10426509608545110

  日期：——
• Scheer, Manfred; Schuster, Kay; Krug, Andre, Chemische Berichte, 1996, vol. 129, # 8, p. 973 - 979
  作者：Scheer, Manfred、Schuster, Kay、Krug, Andre、Hartung, Helmut

  DOI：——

  日期：——