[(η5-C5H5)Fe2Mo(CO)8(μ3-η1:η2:η2-CCPh)] | 738580-48-8

• 英文名称: [(η5-C5H5)Fe2Mo(CO)8(μ3-η1:η2:η2-CCPh)]
• 英文别名: triangulo-μ-[1-(dicarbonyl-η-cyclopentadienylmolybdenum)-2-(σ,η-phenylethyne)]bis(tricarbonyliron)
• CAS: 738580-48-8；86609-27-0
• 化学式: C₂₁H₁₀Fe₂MoO₈
• 分子量: 597.94
• InChiKey: OFFGZSICPJCLPV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  diiron nonacarbonyl 、 (η5-C5H5)Mo(CO)3C2Ph 以 苯 为溶剂， 以14%的产率得到[(η5-C5H5)Fe2Mo(CO)8(μ3-η1:η2:η2-CCPh)]
  参考文献：
  名称：

  Ustynyuk, N. A.; Vinogradova, V. N.; Korneva, V. N., Koordinatsionnaya Khimiya, 1983, vol. 9, p. 363 - 369

  摘要：

  DOI：

文献信息

• Photochemical Reactions of Fe(CO)₅ with Monometal Alkynyls and Free Alkynes:  Synthesis and Characterization of [(η⁵-C₅Me₅)Fe₂Mo(CO)₇{μ₃-η¹:η⁴:η²- C(H)C(Ph)C(Ph)C}] and Diferrocenylquinones
  作者：Pradeep Mathur、Anjan K. Bhunia、Shaikh M. Mobin、Vinay K. Singh、Chimalakonda Srinivasu

  DOI：10.1021/om049739y

  日期：2004.7.1

  Photolysis of a benzene solution containing Fe(CO)(5) and [(eta(5)-C5R5)Mo(CO)(3)(Cequivalent toCPh)] yielded mixed-metal clusters [(eta(5)-C5R5)Fe2Mo(CO)(8)(mu(3)-eta(1):eta(2)-CCPh)] (R = H, 1; Me, 2) and [(eta(5)-C5H5)Fe3Mo(CO)(11)(mu(4)-eta(1):eta(1):eta(2):eta(1)-CCPh)] (3). When a mixture of [(eta(5)-C5Me5)Mo(CO)(3)(Cequivalent toCPh)], Fe(CO)(5), and phenylacetylene was photolyzed, coupling of the acetylide and acetylene was observed and the mixed-metal cluster [(eta(5)-C5Me5)Fe2Mo(CO)(7)(mu(3)-eta(1):eta(4):eta(2)-C(H)C(Ph)C(Ph)C)] (4) was obtained. Interestingly, use of a bulky substituent on the free acetylene in the reaction mixture did not produce analogues of 4. Reaction of Fe(CO)(5) with ferrocenylacetylene produced three different compounds, tetracarbonyl(2-ferrocenylmaleoyl)iron (5), 2,5-diferrocenylquinone (6), and 2,6-diferrocenylquinone (7). All new compounds were characterized by IR and H-1 and C-13 NMR spectroscopy. Structures of 2-7 were established crystallographically.