(trifluoroacetyl)manganese pentacarbonyl 以
gas 为溶剂,
生成 hexamanganese(I)
参考文献:
名称:
Fundamental studies of the energetics and dynamics of ligand dissociation and exchange processes at transition-metal centers in the gas phase: Mn(CO)x+, x = 1-6
Formation of metal-metal bonds by ion-pair annihilation. Dimanganese carbonyls from manganate(I-) anions and manganese(I) cations
作者:K. Y. Lee、D. J. Kuchynka、J. K. Kochi
DOI:10.1021/om00152a010
日期:1987.9.1
Group- and electron-transfer reactions of tetracarbonylferrate(2-)
作者:Yueqian Zhen、Jim D. Atwood
DOI:10.1021/om00054a047
日期:1991.8
Reactions of Fe(CO)4(2-) with metal carbonyl complexes lead to distinct mechanisms. Reaction with metal carbonyl cations gives a two-electron process that we interpret as a CO2+ transfer. Reaction with Mn2(CO)10 occurs by a single-electron transfer producing Fe2(CO)8(2-) and Mn(CO)5-. Reaction with Mn(CO)5Br also occurs by a single-electron transfer. Reaction with Re(CO)5Br could be either SET or direct nucleophilic displacement. Kinetic studies are reported for several reactions.
Richmond, Thomas G.; Crespi, Ann M.; Shriver, Duward F., Organometallics, 1984, vol. 3, # 2, p. 314 - 319
作者:Richmond, Thomas G.、Crespi, Ann M.、Shriver, Duward F.
DOI:——
日期:——
Strauss, Steven H.; Abney, Kent D.; Long, Kim M., Inorganic Chemistry, 1984, vol. 23, # 14, p. 1994 - 1995
作者:Strauss, Steven H.、Abney, Kent D.、Long, Kim M.、Anderson, Oren P.