[Cu2(1,5-diazacyclooctane)2(μ-oxalato)Br2]*CH3OH | 460087-37-0

• 英文名称: [Cu2(1,5-diazacyclooctane)2(μ-oxalato)Br2]*CH3OH
• CAS: 460087-37-0
• 化学式: CH₄O*C₁₄H₂₈Br₂Cu₂N₄O₄
• 分子量: 635.343
• InChiKey: QKSOOUUAVZGZRH-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 1,5-二氮杂环辛烷 、 copper(II) perchlorate hexahydrate 、 sodium oxalate 以 甲醇 、 水 为溶剂， 生成 [Cu2(1,5-diazacyclooctane)2(μ-oxalato)Br2]*CH3OH
  参考文献：
  名称：

  A novel oxalato-bridged dinuclear copper(II) complex with diazamesocyclic terminal ligand: crystal structure, spectroscopy and magnetism

  摘要：

  The synthesis of a new oxalato-bridged dinuclear Cu(II) complex, [Cu-2(DACO)(2)(mu-ox)Br-2].CH3OH (1), where DACO = 1,5-diazacyclooctane, together with its spectral and magnetic characterization, are reported. Crystal structure of I has been determined by X-ray diffraction analysis, which is made up of centrosymmetric dinuclear [Cu-2(DACO)(2)(mu-ox)Br-2] unit and noncoordinated methanol molecule, assembling into a novel two-dimensional step-like extended network through hydrogen bonds. The magnetic susceptibility indicates that complex I is anti-ferromagnetic coupling with 2J= -242 cm(-1). The strength of the exchange interaction is discussed on the basis of the structural feature. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)00810-1